Modified HIMS Process Using Dual-Layer Surfactant Agglomeration

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Solution Overview

Problem

Existing processes for separating ores from mixtures, particularly those involving magnetic particles, suffer from low yield and inefficiency due to insufficient attachment of magnetic particles to ores and high entrainment of gangue, leading to suboptimal separation results.

Innovation Solution

A process involving the contact of ore mixtures with magnetic particles in a dispersion medium, followed by separation using an external magnetic field in a magnetizable device, with subsequent steps to dissociate and recover the magnetic particles and ores, ensuring stable agglomeration and minimal gangue entrainment, utilizing hydrophobic interactions and surfactants to enhance separation efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If magnetic particles are used to separate ores from mixtures, then separation capability is improved, but attachment strength between magnetic particles and ores is insufficient

Engineering Contradiction:
Improveseparation capabilityVSAvoidattachment strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent introduces a two-layer surfactant system as an intermediary between magnetic particles and ores. The first layer (collecting agent) attaches to the ore surface, while the second layer (frothing agent) attaches to the magnetic particle surface, creating a stable bridge that significantly enhances attachment strength and prevents detachment during separation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite structure where magnetic particles are coated with a dual-layer surfactant system. This composite material combines the magnetic properties of the particles with the surface-active properties of the surfactants, enabling both strong attachment to ores and stable aggregation in the dispersion medium

Inventive Principle:
Principle #40Composite materials

2Reliability

If magnetic separation is performed, then ore separation is achieved, but gangue entrainment is high

Engineering Contradiction:
Improveore separationVSAvoidgangue entrainment
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies different surfactant layers with specific local functions: the first layer targets the ore surface with collecting properties, while the second layer targets the magnetic particle surface with frothing properties. This localized functional differentiation ensures selective attachment and minimizes non-specific gangue entrainment

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent modifies the surface charge parameters of both the magnetic particles and ores through surfactant adsorption. By controlling the concentration and type of surfactants, the surface charge density and zeta potential are adjusted to optimize selective attachment and reduce gangue contamination

Inventive Principle:
Principle #35Parameter changes

3Productivity

If magnetic particles aggregate with ores, then separation yield is improved, but agglomerate stability is insufficient

Engineering Contradiction:
Improveseparation yieldVSAvoidagglomerate stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent ensures continuous stabilization of the agglomerates through the dual-layer surfactant system. The first layer provides continuous attachment to the ore, while the second layer provides continuous stabilization at the magnetic particle interface, maintaining agglomerate integrity throughout the separation process

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent creates a stable interface model where the surfactant layers replicate the optimal attachment configuration. The structured arrangement of surfactant molecules at the interface between magnetic particles and ores creates a reproducible, stable configuration that maintains agglomerate integrity under varying process conditions

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process achieves a high yield of the desired ore with minimal gangue entrainment, improving the efficiency of ore separation by ensuring strong and stable agglomeration of magnetic particles with ores and effective separation from gangue.

Implementation Method 1

utilizing hydrophobic interactions and surfactants to enhance separation efficiency

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

separation using an external magnetic field in a magnetizable device

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 3

separating the aggregate of at least one first material and at least one magnetic particle from the dispersion

Methodology Applied
Scientific EffectMagnetism: Magnetism

Data Source

PatentEP2519356B1Modified high intensity magnetic separation (HIMS) process
Publication Date: 2019.06.19 BASF SE

AI summary

A process for separating at least one first material from a mixture comprising said at least one first material and at least one second material is provided. The process comprises the step of contacting the mixture with at least one magnetic particle in the presence of at least one dispersion medium to form the agglomerates of the at least one first material and the magnetic particle.