3D HNOR Memory Fabrication via Protective Layer Crystallization

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Solution Overview

Problem

Current fabrication processes for 3-dimensional arrays of NOR-type memory strings face challenges in achieving high charge carrier mobility and conductivity, which are crucial for efficient memory operations.

Innovation Solution

The process involves forming active stacks with channel regions protected by a protective layer, followed by crystallization of silicon materials with SiGe, which induces greater grain boundaries, enhancing charge carrier mobility and conductivity. This includes multiple trench-forming steps, deposition of channel and protective materials, and filling with conductive materials to create local word lines connected to decoding circuitry.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fabrication processes are used for 3D NOR memory strings, then manufacturing simplicity is maintained, but charge carrier mobility and conductivity are insufficient

Engineering Contradiction:
Improvecharge carrier mobilityVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

A protective layer is deposited over the channel region before charge-trapping material deposition. This preliminary protective action prevents charge-trapping material from contaminating the channel region during subsequent processing steps, enabling the use of materials that would otherwise be incompatible with direct channel exposure while maintaining high charge carrier mobility.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The protective layer is applied specifically to the channel region, providing localized protection where it is most needed. This allows different regions of the structure to have different properties: the channel region maintains high purity and mobility while other regions can accommodate charge-trapping material deposition and processing.

Inventive Principle:
Principle #3Local quality

2Reliability

If protective layer is deposited over channel region, then charge carrier mobility is improved through grain boundary enhancement, but manufacturing steps increase

Engineering Contradiction:
ImproveconductivityVSAvoidnumber of fabrication steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The protective layer serves multiple functions simultaneously: it protects the channel region from charge-trapping material contamination, provides a platform for controlled deposition, and enables grain boundary formation through crystallization. By merging these functions into a single layer, the patent reduces overall device complexity despite adding a fabrication step.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The protective layer is formed using composite material deposition and crystallization processes that create grain boundaries within the layer structure. This composite approach, combining amorphous deposition with crystalline formation, enhances charge carrier mobility while integrating seamlessly with existing fabrication workflows.

Inventive Principle:
Principle #40Composite materials

3Reliability

If amorphous silicon and protective material are deposited then crystallized in anneal step, then charge carrier mobility and current density are enhanced, but processing temperature requirements increase

Engineering Contradiction:
Improvecurrent densityVSAvoidanneal temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs parameter changes in the annealing process, optimizing temperature, time, and atmospheric conditions to achieve crystallization of the amorphous silicon and protective material. By carefully controlling these parameters, the process achieves grain boundary formation and phase transformation at temperatures that enhance charge carrier mobility without causing damage to other structure components.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in highly efficient HNOR arrays with improved charge carrier mobility, conductivity, and current densities, enabling better performance in memory operations.

Implementation Method 1

Both the silicon for the channel regions and the protective material may be deposited in amorphous form and are subsequently crystallized in an anneal step

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

Both the silicon for the channel regions and the protective material may be deposited in amorphous form

Methodology Applied
Scientific EffectAmorphous deposition: Deposition (physical)

Implementation Method 3

Both the silicon for the channel regions and the protective material may be deposited in amorphous form and are subsequently crystallized in an anneal step

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS11217600B2Process for a 3-dimensional array of horizontal NOR-type memory strings
Publication Date: 2022.01.04 SUNRISE MEMORY CORP
  • US11217600B2 patent drawing
  • US11217600B2 patent drawing
  • US11217600B2 patent drawing

AI summary

In the highly efficient fabrication processes for HNOR arrays provided herein, the channel regions of the storage transistors in the HNOR arrays are protected by a protective layer after deposition until the subsequent deposition of a charge-trapping material before forming local word lines. Both the silicon for the channel regions and the protective material may be deposited in amorphous form and are subsequently crystallized in an anneal step. The protective material may be silicon boron, silicon carbon or silicon germanium. The protective material induces greater grain boundaries in the crystallized silicon in the channel regions, thereby providing greater charge carrier mobility, greater conductivity and greater current densities.