Hole Transporting Compound for OLED Cost Reduction

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Solution Overview

Problem

Organic light emitting diode (OLED) devices are costly due to the high expense of light emitting compounds, which make up 40-50% of the light emitting layer, and there is a need for materials that maintain optoelectronic properties while reducing production costs.

Innovation Solution

Development of a compound that can function as a hole transporter in the light emitting layer, allowing for a reduction in the amount of expensive light emitting compounds needed, by incorporating a compound of general formula (I) into the OLED structure, which enables efficient hole transport and maintains device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If light emitting compounds are used in high amounts (40-50% wt) to maintain optoelectronic properties, then device performance is improved, but manufacturing cost increases significantly

Engineering Contradiction:
Improveoptoelectronic propertiesVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces a hole transporting material as an intermediary substance in the light emitting layer. This material mediates between the expensive light emitting compound and the device structure, enabling reduced light emitting compound concentration (to 5-20% wt) while maintaining hole transport functionality and overall device performance through its charge transport capability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The hole transporting material performs multiple functions: it transports holes through the light emitting layer, enables charge balance, and allows reduction of light emitting compound concentration. This multi-functionality resolves the contradiction by providing the necessary charge transport without requiring high concentrations of expensive light emitting materials

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of manufacture

If light emitting compound concentration is reduced to lower cost, then manufacturing cost decreases, but device performance may deteriorate

Engineering Contradiction:
Improvemanufacturing costVSAvoidoptoelectronic properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the compositional parameters of the light emitting layer by reducing light emitting compound concentration to 5-20% wt and supplementing with hole transporting material. This parameter change maintains device performance by compensating for reduced light emitting compound through enhanced hole transport capability, thus lowering cost without sacrificing performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the compound reduces manufacturing costs significantly without compromising the optoelectronic properties of OLED devices, such as luminance, current density, and external quantum efficiency, while also extending device lifetime.

Implementation Method 1

The compounds of the present invention are much cheaper to manufacture than light emitting compounds such as phosphorescent iridium complexes therefore the cost of manufacturing the devices of the invention is significantly reduced. Moreover it has also been discovered that the incorporation of the compounds of the present invention into the light emitting layer of an OLED does not adversely impact on the lifetime of the device.

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Data Source

PatentUS10205108B2Compound
Publication Date: 2019.02.12 CAMBRIDGE DISPLAY TECH LTD
  • US10205108B2 patent drawing
  • US10205108B2 patent drawing
  • US10205108B2 patent drawing

AI summary

The present invention relates to a compound of general formula (I) which can transport holes in an organic optoelectronic device, and to blends and solutions comprising the compound of general formula (I):whereinX is C, Si or Ge;A is a group of formula (II)wherein Z is N, P, NH, O or S;E is C1-10 alkyl or H;W is substituted or unsubstituted C5-14 aryl or substituted or unsubstituted C6-16 alkyl;e is an integer from 1 to 4; andz is 1 or 2;B, C and D are each independently A, H, C1-C12 alkyl, C5-14 aryl or OH; anda, b, c and d are each independently an integer from 1 to 5.