Hole-Transporting Ink Composition for Uniform OLED Solution Processing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing organic light-emitting devices (OLEDs) face challenges in achieving high luminance, efficiency, and long lifespan while maintaining low driving voltage, particularly due to issues with wettability and in-pixel uniformity during the solution process.

Innovation Solution

A hole-transporting ink composition comprising an adhesion-promoting compound and a hole-transporting compound, which forms a self-assembled monolayer on the substrate or electrode, improving wettability and in-pixel uniformity, and includes a solvent that enhances the formation of a uniform layer in the OLED structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional solution processes are used for OLED fabrication, then manufacturing simplicity is maintained, but wettability and in-pixel uniformity deteriorate

Engineering Contradiction:
Improvein-pixel uniformityVSAvoidsolution process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by introducing a hole-transporting ink composition that forms a self-assembled monolayer on the substrate or electrode before subsequent OLED layer deposition. This pre-formed layer improves wettability and in-pixel uniformity of subsequent layers, addressing the uniformity issue without requiring complex process modifications later in fabrication

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses composite materials by combining a hole-transporting compound with specific additives in the ink composition. The composite formulation includes compounds with specific molecular structures (e.g., carbazole derivatives, triphenylamine derivatives) that work synergistically to improve both wettability and uniformity while maintaining solution-processability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If high luminance and efficiency are achieved in OLEDs, then driving voltage increases

Engineering Contradiction:
ImproveluminanceVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSUse of energy by stationary object

Solution Approach 1:

The patent applies parameter changes by optimizing the molecular structure parameters of the hole-transporting compounds and adjusting the composition ratios in the ink formulation. Specific structural modifications (e.g., adding electron-donating or electron-withdrawing groups) tune the HOMO/LUMO energy levels and hole mobility, enabling high luminance at reduced driving voltages

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating regions with different material properties within the hole transport layer. The self-assembled monolayer provides localized improvement in interfacial properties and charge transport, while the bulk layer maintains overall hole transport function, allowing efficient charge injection without uniform voltage increase across the entire device

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution process results in OLEDs with excellent characteristics such as high luminance, high efficiency, long lifespan, and low driving voltage, addressing the limitations of existing technologies.

Implementation Method 1

which forms a self-assembled monolayer on the substrate or electrode

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

The adhesion-promoting compound may include a self-assembled monomolecule for forming a self-assembled monolayer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250257079A1Hole transporting ink composition, light-emitting devie, and method of preparing the light-emitting device
Publication Date: 2025.08.14 SAMSUNG DISPLAY CO LTD
  • US20250257079A1 patent drawing
  • US20250257079A1 patent drawing
  • US20250257079A1 patent drawing

AI summary

According to one aspect of the invention, a hole-transporting ink composition for a light emitting device, the hole-transporting ink composition includes an adhesion-promoting compound represented by Formula 1 and a hole-transporting compound:A1-B1—C1  Formula 1wherein, in Formula 1, the variables are defined above.