Magnetically Enhanced Hollow Cathode Plasma Source for Low-Temp Diamond Films

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Solution Overview

Problem

Conventional methods for depositing diamond and diamond-like coatings require high temperatures, making it challenging to achieve low-temperature deposition of high-density plasma-chemical vapor deposition (LT-HDP-CVD) of diamond and DLC films.

Innovation Solution

A pulse magnetically enhanced LT-HDP-CVD apparatus and method utilizing a hollow cathode, anode, and magnetic field geometry to create a perpendicular magnetic field, along with a power supply generating negative voltage pulses to dissociate and ionize feed gas molecules, allowing for low-temperature deposition of diamond and DLC films.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional HFCVD or microwave assisted CVD methods are used to deposit diamond and DLC films, then high quality films can be achieved, but high temperature is required which limits application to temperature-sensitive substrates

Engineering Contradiction:
Improvesubstrate temperatureVSAvoidfilm quality
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The invention changes the plasma generation parameters by using pulsed high power magnetic fields instead of continuous thermal heating, enabling film deposition at low substrate temperatures while maintaining high film quality through controlled plasma conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system employs pulsed power supply with specific duty cycles to generate intermittent high-density plasma, allowing sufficient time for substrate cooling between pulses while accumulating film material during active deposition phases

Inventive Principle:
Principle #19Periodic action

2Power

If high power is applied to generate sufficient plasma density for LT-HDP-CVD, then low temperature deposition is enabled, but arcing and plasma instability occur

Engineering Contradiction:
Improveplasma powerVSAvoidplasma stability
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

Pulsed power application with controlled duty cycles allows high power density during active phases while providing cooling intervals, preventing thermal runaway and arcing that would occur with continuous high power application

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The system dynamically adjusts power levels and pulse characteristics based on real-time plasma conditions, optimizing plasma density while maintaining stability by responding to changing operational parameters

Inventive Principle:
Principle #15Dynamics

3Productivity

If magnetic field is applied to enhance plasma density, then deposition rate improves, but device complexity increases due to additional magnet assemblies

Engineering Contradiction:
Improvedeposition rateVSAvoidmagnetic field generation system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The magnet assembly serves multiple functions: generating the magnetic field for plasma confinement, providing structural support for the plasma source, and enabling both sputtering and CVD deposition modes through the same device architecture

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention combines the magnetic field generation system with the existing plasma source structure, integrating magnet assemblies into the cathode or anode components rather than adding separate external magnetic field generators

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the deposition of diamond and DLC films at low temperatures with high density and controlled plasma density, reducing the probability of arcing and improving film quality and uniformity.

Implementation Method 1

a row of permanent magnets or electromagnets that are positioned adjacent to the gap in order to form a magnetic field in the gap

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

providing negative voltage pulses to dissociate and ionize feed gas molecules

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

igniting volume plasma discharge

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 4

a hollow cathode connected to a power supply... a cathode magnet assembly configured to generates magnetic field lines substantially perpendicular to a surface of the hollow cathode

Methodology Applied
Scientific EffectCathodic arc discharge: Cathodic Arc Deposition

Implementation Method 5

a flowing liquid that cools and controls the temperature of the hollow cathode

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentUS11821068B2Magnetically enhanced high density plasma-chemical vapor deposition plasma source for depositing diamond and diamond-like films
Publication Date: 2023.11.21 IONQUEST LLC
  • US11821068B2 patent drawing
  • US11821068B2 patent drawing
  • US11821068B2 patent drawing

AI summary

A magnetically enhanced plasma apparatus includes a hollow cathode target assembly; an anode positioned on top of the hollow cathode target assembly, thereby forming a gap between the anode and the hollow cathode target assembly; a cathode magnet assembly; a row of magnets that generate a magnetic field in the gap and a magnetic field on a surface of the hollow cathode target assembly with the cathode magnet assembly such that magnetic field lines are substantially perpendicular to a surface of the hollow cathode target assembly; an electrode positioned adjacent to the row of magnets behind the gap; a first radio frequency (RF) power supply coupled to the electrode, wherein the electrode is coupled to ground through an inductor; and a second radio frequency (RF) power supply coupled to the hollow cathode target assembly. The second RF power supply ignites and sustains plasma in the hollow cathode target assembly. A frequency and power of the second RF power supply are selected to increase at least one of a degree of dissociation of feed gas molecules and degree of ionization of feed gas atoms. A frequency and power of the first RF power supply are selected to increase a degree of dissociation of feed gas molecules to form a layer from sputtering hollow cathode target material onto a substrate.