Hollow Cone Microscope Illumination for Raman Resolution

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Solution Overview

Problem

Current microspectrometry techniques, such as Raman and microellipsometry, face limitations in axial and lateral resolution, leading to low signal-to-noise ratios and reduced intensity of the excitation beam due to the use of confocal and dark field illumination methods, which are unfavorable for thin samples and require expensive filters with high rejection rates.

Innovation Solution

An optical device with hollow cone illumination and point focusing, utilizing a combination of conical lenses and an afocal optical system, generates a collimated incident light beam focused to a point, creating a cylindrical light beam with a dark background, allowing for improved axial and lateral resolution while maintaining signal intensity, and incorporating a collection mirror to separate the Raman backscatter signal effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If confocal illumination is used to improve axial resolution, then axial resolution is improved, but signal intensity is reduced due to beam energy removal

Engineering Contradiction:
Improveaxial resolutionVSAvoidsignal intensity
Core Design Contradiction:
Measurement precisionVSIllumination intensity

Solution Approach 1:

Instead of removing the central part of the beam (dark-field approach), the invention inverts the approach by using a hollow cone beam that concentrates energy in an annular region while maintaining a dark center. This allows the peripheral rays to provide both the axial resolution improvement and sufficient signal intensity without the need to block the central beam.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The invention changes the angular distribution parameter of the illumination beam from a conventional Gaussian profile to a hollow cone profile with a specific angular range. This parameter change allows the beam to achieve confocal-like axial resolution while maintaining higher overall intensity by distributing energy in an annular pattern rather than removing it.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If dark field illumination is used to improve signal-to-noise ratio, then signal-to-noise ratio is improved, but light intensity collected is greatly reduced

Engineering Contradiction:
Improvesignal-to-noise ratioVSAvoidlight intensity collected
Core Design Contradiction:
Measurement precisionVSIllumination intensity

Solution Approach 1:

The invention inverts the conventional dark-field approach by using a hollow cone beam that provides a dark center for background suppression while maintaining an annular bright region that collects sufficient scattered light. This inversion allows simultaneous achievement of high signal-to-noise ratio and adequate light collection efficiency.

Inventive Principle:
Principle #13The other way round (Inversion)

3Manufacturing precision

If laser beam is focused to a point to achieve micrometric lateral resolution, then lateral resolution is improved, but axial resolution remains poor due to optical radiation outside focal point

Engineering Contradiction:
Improvelateral resolutionVSAvoidaxial resolution
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The invention segments the conventional focused beam into a hollow cone structure where the energy is distributed along a conical path rather than concentrated in a single focal point. This segmentation of the beam energy along the axial direction maintains lateral resolution while improving axial resolution by reducing out-of-focus radiation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from a point-focused beam (zero-dimensional focus) to a hollow cone beam that extends in the axial dimension. By adding this dimensional aspect, the beam maintains its lateral focusing capability while distributing energy more favorably along the axial direction, thereby improving axial resolution.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Measurement precision

If high-rejection filters are used to extract Raman signal, then Raman signal extraction is improved, but device complexity and cost increase

Engineering Contradiction:
ImproveRaman signal extractionVSAvoidfilter complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention extracts the Rayleigh scattered light (which is the main obstacle to Raman signal detection) by using the hollow cone beam geometry that directs most Rayleigh scattering away from the collection path. This extraction of the dominant background signal reduces the filtering burden and allows simpler filters to be used.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enhances the signal-to-noise ratio and axial resolution in microspectrometry, reduces the need for high-rejection filters, and allows for more efficient Raman signal extraction, particularly for thin samples, by focusing the illumination to a micrometric area and effectively filtering out the excitation laser beam.

Implementation Method 1

the first conical lens being arranged to receive said collimated incident light beam and to form a first hollow cone light beam

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

the second conical lens being arranged to receive said first hollow cone light beam and to form a cylindrical light beam with a dark background

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 3

the optical objective is arranged to receive said darkfield cylindrical light beam and to form a second hollow cone light beam and to focus said hollow cone light beam at a point of micrometric dimensions in the image focal plane

Methodology Applied
Scientific EffectFocusing: Focusing

Data Source

PatentEP3627207B1Optical device for conoscopic lighting with hollow cone for optical microscope and method for optical microscopy in conoscopy
Publication Date: 2024.10.16 HORIBA FRANCE SAS
  • EP3627207B1 patent drawingFigure 1~3
  • EP3627207B1 patent drawingFigure 4A~5A
  • EP3627207B1 patent drawingFigure 5B~6

AI summary

The present invention relates to a microscopy method and a hollow cone optical illumination device for a microscope. According to the invention, the illumination device comprises a first conical lens (1) adapted to receive a collimated incident light beam (10) and to form a conical light beam (20), a second conical lens (5) arranged to receive said conical light beam (20, 40) and to form a cylindrical light beam with a dark background (50), and an optical objective (6) having an image focal plane (12) arranged to receive said cylindrical light beam with a dark background (50), to form a hollow cone light beam (60), and to focus said hollow cone light beam (60) at a point (18) in the image focal plane (12).