Hollow Cylinder Catalyst Support for Ethylene Oxide Reactors

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Solution Overview

Problem

Conventional ethylene oxide reactor systems face challenges in achieving a balance between high catalyst packing density and low pressure drop during the partial oxidation of ethylene, as increased packing density often results in undesirable pressure drops.

Innovation Solution

A reactor system with a packed catalyst bed featuring a hollow cylinder geometric configuration for the catalyst support material, optimizing the ratio of outside diameter to inside diameter and length, which reduces pressure drop while maintaining high packing density, by using a combination of silver as the catalytic component and rare earth metals as promoters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If catalyst packing density is increased to improve catalyst performance, then catalyst performance is improved, but pressure drop across the reactor increases undesirably

Engineering Contradiction:
Improvecatalyst performanceVSAvoidpressure drop
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent applies parameter changes by optimizing the geometric parameters of hollow cylinder catalyst supports, specifically the ratio of outside diameter to inside diameter and the ratio of length to outside diameter. By changing these dimensional parameters within specific ranges, the patent achieves high catalyst packing density while controlling pressure drop across the reactor bed.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes hollow cylinder catalyst supports with controlled porosity characteristics. The hollow cylindrical geometry provides internal void space that reduces inter-particle resistance to flow while maintaining high external packing density, effectively creating a porous-like flow path structure that balances catalyst contact efficiency with pressure drop management.

Inventive Principle:
Principle #31Porous materials

2Quantity of substance

If hollow cylinder catalyst support dimensions are changed to optimize packing density, then packing density improves, but pressure drop characteristics may worsen

Engineering Contradiction:
Improvecatalyst packing densityVSAvoidpressure drop
Core Design Contradiction:
Quantity of substanceVSStress or pressure

Solution Approach 1:

The patent systematically varies the geometric parameters of hollow cylinder catalyst supports, including outside diameter, inside diameter, and length, within specifically defined ratio ranges. This parameter optimization allows the catalyst bed to achieve high packing density while maintaining favorable pressure drop characteristics through controlled voidage and flow paths.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The hollow cylinder catalyst support represents a composite structural design combining solid catalytic material with internal hollow space. This composite geometry provides both the necessary catalyst surface area for high packing density and internal void volume for reduced flow resistance, effectively combining the benefits of dense packing with low pressure drop.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration achieves a better balance between tube packing density and pressure drop, allowing for increased catalyst performance with reduced incremental pressure drop, and can be used in the production of ethylene oxide, ethylene glycol, and other chemicals.

Implementation Method 1

the difficulty in having a proper balance between the pressure drop that occurs across the catalyst bed during the operation of the ethylene oxide process and the catalyst bed packing density

Methodology Applied
Scientific EffectPressure drop: Pressure Drop

Implementation Method 2

a feedstream containing ethylene and oxygen is passed over a bed of catalyst contained within a reaction zone that is maintained at certain reaction conditions

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

One method for manufacturing ethylene oxide is by the catalyzed partial oxidation of ethylene with oxygen

Methodology Applied
Scientific EffectPartial oxidation: Oxidation

Data Source

PatentUS8043575B2Reactor system and process for the manufacture of ethylene oxide
Publication Date: 2011.10.25 SHELL USA INC
  • US8043575B2 patent drawing
  • US8043575B2 patent drawing
  • US8043575B2 patent drawing

AI summary

A reactor system for the oxidation of ethylene to ethylene oxide. The reactor system includes a reactor tube that contains a packed bed of shaped support material that can include a catalytic component. The shaped support material has a hollow cylinder geometric configuration. The reactor system has specific combinations of reactor tube and catalyst system geometries.