Hollow Graphite Catalyst Carrier for Fuel Cell Gas Diffusion

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Solution Overview

Problem

Conventional fuel cell electrode catalyst materials face challenges in uniformly supplying gases to the catalyst layer, leading to non-uniform gas concentration distribution and reduced power generation performance due to limited gas diffusion paths and aggregation of catalyst particles.

Innovation Solution

The use of graphite particles with hollow structures and through-holes or recesses as catalyst carriers, which support catalyst particles and enhance gas diffusibility by providing additional gas diffusion paths, preventing catalyst particle aggregation, and maintaining a stable dispersion of catalysts for improved power generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional carbon particles are used as catalyst carriers, then the catalyst layer can be formed, but gas diffusion is limited and power generation performance deteriorates

Engineering Contradiction:
Improvepower generation performanceVSAvoidgas diffusion rate
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent employs graphite particles with a porous hollow structure as catalyst carriers. These particles contain multiple through-holes that penetrate from the outer surface to the inner hollow space, creating efficient gas diffusion paths. The porous structure allows reactant gases to reach catalyst particles distributed throughout the hollow space, significantly improving gas diffusion rates and power generation performance compared to conventional solid carbon particles.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention transitions from conventional two-dimensional surface-supported catalysts to three-dimensional hollow structure-supported catalysts. By distributing catalyst particles throughout the hollow interior space of graphite particles rather than only on the outer surface, the catalyst utilization efficiency increases, and gas diffusion paths are extended into the third dimension, enhancing overall reaction efficiency.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Productivity

If catalyst particles are densely packed to increase catalyst loading, then catalyst activity increases, but catalyst aggregation occurs and uniform gas distribution is compromised

Engineering Contradiction:
Improvecatalyst activityVSAvoidcatalyst dispersion uniformity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent divides the catalyst layer into multiple independent hollow graphite particles, each containing a controlled number of catalyst particles. This segmentation prevents large-scale catalyst aggregation while maintaining high catalyst loading within each particle. The hollow structure of each particle acts as an isolated compartment, ensuring uniform catalyst distribution throughout the catalyst layer and preventing aggregation between particles.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates local high-concentration catalyst regions within the hollow spaces of graphite particles while maintaining overall uniform distribution. Catalyst particles are concentrated within the bounded hollow space of each graphite particle, creating locally optimized catalytic zones. This local quality approach allows high catalyst activity within each particle while preventing macroscopic aggregation across the catalyst layer.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves power generation performance by ensuring uniform gas distribution and maintaining catalyst activity over time, reducing the risk of catalyst aggregation and enhancing the surface area for reaction, thus increasing the fuel cell's efficiency and longevity.

Implementation Method 1

gases pass through voids between carbon particles as a gas diffusion path, and are supplied to the entire catalyst layer

Methodology Applied
Scientific EffectGas diffusion: Diffusion

Implementation Method 2

Each of the catalyst layers included in the fuel cell includes a catalyst of platinum or the like and a catalyst carrier of carbon particles or the like as an electrode catalyst material

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10388966B2Electrode catalyst material, and fuel cell
Publication Date: 2019.08.20 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US10388966B2 patent drawing
  • US10388966B2 patent drawing
  • US10388966B2 patent drawing

AI summary

An electrode catalyst material includes graphite particles and catalyst particles. Each of the graphite particles has a hollow structure that includes an outer shell, and the outer shell has at least one of a through-hole and a recess. Each of the catalyst particles is supported by the at least one of through-hole and recess.