Lightweight Hollow Particle Composite for Wellbore Cementing

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Solution Overview

Problem

Current methods for producing lightweight cement slurries for wellbore cementing fail to meet all requirements, including suitable compressive and tensile strength, ease of mixing and blending, and resistance to hydrostatic pressures, with existing additives either compromising mechanical properties or being difficult to handle and execute in the field.

Innovation Solution

A lightweight hollow particle composite is created by heating calcium carbonate with clay and an inorganic material, such as glass, to produce a hollow core with cement grains adhered or embedded on its surface, which is then used in a slurry to cement well casings, offering improved handling and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If excess water is added to lower slurry density, then hydrostatic pressure is reduced, but compressive strength and tensile strength deteriorate

Engineering Contradiction:
Improvehydrostatic pressureVSAvoidcompressive strength
Core Design Contradiction:
Stress or pressureVSStrength

Solution Approach 1:

The invention changes the density parameter of the cement slurry by incorporating hollow spherical particles with densities of 0.5-2.0 g/cm³, allowing density reduction from typical 15-18 ppg to 8-12 ppg while maintaining strength through the reactive surface of hollow particles that promote cement hydration and bond formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system combining cement matrix with hollow spherical particles (such as hollow glass spheres, hollow pozzolanic spheres, or synthetically produced hollow particles). This composite structure provides both the density reduction needed for low hydrostatic pressure and the mechanical strength through the interfacial bond between cement and hollow particle surfaces

Inventive Principle:
Principle #40Composite materials

2Stress or pressure

If hollow pozzolanic spheres are used to reduce density, then slurry density is lowered, but resistance to hydrostatic pressure deteriorates

Engineering Contradiction:
Improveslurry densityVSAvoidresistance to hydrostatic pressure
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The invention specifies hollow particles with wall thicknesses of 1-50 micrometers and densities of 0.5-2.0 g/cm³, optimized to withstand hydrostatic pressures exceeding 3,000 psi while maintaining the desired slurry density reduction. This parameter optimization resolves the contradiction between density reduction and pressure resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces fragile hollow pozzolanic spheres with more durable hollow particles having improved mechanical properties and pressure resistance. The hollow particles are designed to maintain structural integrity under hydrostatic loading, eliminating the reliability issue associated with conventional hollow spheres

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Stress or pressure

If foamed cement is used to reduce density, then slurry density is lowered, but ease of operation deteriorates

Engineering Contradiction:
Improveslurry densityVSAvoidease of mixing
Core Design Contradiction:
Stress or pressureVSEase of operation

Solution Approach 1:

The invention uses hollow spherical particles as an intermediary substance to reduce slurry density without requiring foaming agents or complex foam generation equipment. These particles mix readily with cement slurry and provide density reduction through their low density and high void fraction, simplifying field operations

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention extracts the harmful complexity of foaming operations by replacing foam-based density reduction with particle-based density reduction. This eliminates the need for special equipment, trained personnel, and complex process control, greatly improving ease of operation

Inventive Principle:
Principle #2Taking out (Extraction)

4Stress or pressure

If non-reactive lightweight additives are used, then slurry density is lowered, but compressive strength deteriorates

Engineering Contradiction:
Improveslurry densityVSAvoidcompressive strength
Core Design Contradiction:
Stress or pressureVSStrength

Solution Approach 1:

The invention changes the surface properties of hollow particles to be chemically reactive with cement, creating strong interfacial bonds. The reactive surface promotes cement hydration and adhesion, transforming non-reactive hollow spheres into active components that enhance both density reduction and compressive strength development

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite provides enhanced compressive strength, reduced hydrostatic pressure, and improved handling characteristics, allowing for effective cementing in deep wells with lower operating costs and hazards, while maintaining mechanical properties and ease of use.

Implementation Method 1

heating calcium carbonate, clay and an inorganic material such as inorganic glass to the temperature at which calcium carbonate decomposes and the inorganic material begins to melt

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

As the inorganic material begins to melt, gases are evolved

Methodology Applied
Scientific EffectGas evolution: Decomposition (biological)

Implementation Method 3

The gases cause the semi-molten inorganic material to expand outwardly

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 4

The presence of clay imparts rigidity to the inorganic material and allows the hollow core to retain its shape at elevated temperatures

Methodology Applied
Scientific EffectRigidity enhancement:

Implementation Method 5

Hydraulic cements are cements that set and develop compressive strength due to hydration

Methodology Applied
Scientific EffectHydration: Mineral Hydration

Data Source

PatentUS9765253B2Lightweight hollow particles for use in cementing
Publication Date: 2017.09.19 BAKER HUGHES CO
  • US9765253B2 patent drawing
  • US9765253B2 patent drawing
  • US9765253B2 patent drawing

AI summary

A lightweight composite having an activated surface contains a lightweight hollow core particle having cement grains which may be adhered to the hollow core or embedded in the surface of the hollow core. The hollow core particle may be prepared from calcium carbonate and a mixture of clay, such as bentonite, and a glassy inorganic material, such as glass spheres, glass beads, glass bubbles, borosilicate glass and fiberglass.