Hollow Titanium Silicate Catalyst with Amorphous Silica Binder
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Solution Overview
Problem
Existing catalysts with titanium silicate molecular sieves face challenges in achieving high crushing strength while maintaining a high content of molecular sieve, leading to reduced catalytic activity and increased production costs.
Innovation Solution
A catalyst with a hollow titanium silicate structure and an amorphous silica binder, where the binder content is 3-15 wt% and the titanium silicate content is 85-97 wt%, allowing for high crushing strength and increased catalytic activity through enhanced binding and surface interaction.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If the amount of binder is increased to increase crushing strength, then the crushing strength is improved, but the content of titanium silicate decreases, leading to decreased catalytic activity
Solution Approach 1:
The patent changes the chemical composition parameters of the binder from conventional alumina-based binders to silica-based binders (silica sol, silicon carbide, or amorphous silica). This parameter change allows the binder to chemically bond with titanium silicate molecular sieves through siloxane bonds, creating a stronger interface that enables higher binder content (5-20 wt%) without sacrificing catalytic activity. The chemical affinity between silica binder and titanium silicate creates a synergistic effect where the binder becomes part of the catalytic structure rather than just a mechanical support.
2Productivity
If the content of titanium silicate is increased to improve catalytic activity, then the catalytic activity is improved, but the crushing strength decreases
Solution Approach 1:
The patent creates a composite catalyst material consisting of titanium silicate molecular sieves (80-95 wt%) combined with silica-based binders (5-20 wt%). This composite structure leverages the high catalytic activity of titanium silicate while using the silica binder to provide mechanical strength. The chemical bonding between silica and titanium silicate creates an integrated composite where the binder reinforces the molecular sieve structure rather than merely holding it together mechanically, enabling the catalyst to maintain both high activity and sufficient strength.
3Strength
If conventional shaping methods are used to increase catalyst strength, then the crushing strength is improved, but the equipment cost and operation cost increase
Solution Approach 1:
The silica-based binder performs multiple functions simultaneously: it provides mechanical strength, creates chemical bonds with titanium silicate, and enhances the overall structural integrity of the catalyst. This self-reinforcing mechanism eliminates the need for complex shaping processes, additional strengthening agents, or extensive mechanical reinforcement. The catalyst can be prepared through simpler mixing and shaping methods while achieving the required strength, thereby reducing both equipment investment and operational costs.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The catalyst achieves high conversion of hydrogen peroxide and selectivity for epoxides, ensuring high catalytic activity and industrial requirements are met while maintaining sufficient strength.
Implementation Method 1
said binder being an amorphous silica... enhanced binding and surface interaction
Implementation Method 2
the adsorption capacity of benzene measured for the molecular sieve sample... there is a hysteresis loop between the adsorption isotherm and the desorption isotherm
Implementation Method 3
the epoxidation of olefin using hydrogen peroxide as an oxidizer and using a titanium silicate as the catalyst to prepare an oxygen-containing organic compound
Data Source
AI summary
Disclosed herein are a catalyst, a preparation process thereof, and a process of epoxidizing olefin using the catalyst. The catalyst contains a binder and a titanium silicate as specified. The catalyst disclosed herein has high strength, and shows high catalytic activity in the epoxidation of olefins.


