Homogenized Tobacco Material with Basic pH Modifier

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Solution Overview

Problem

Existing reconstitution processes for homogenized tobacco materials, such as casting or 'cast leaf' processes, result in significant nicotine loss during the drying step, limiting the transfer yield of nicotine to inhalable aerosols in heated aerosol-generating articles when heated to relatively low temperatures.

Innovation Solution

Incorporating a basic pH modifier with low water solubility, such as magnesium hydroxide, into the homogenized tobacco material to enhance nicotine release and reduce nicotine loss during production, while maintaining a lower heating temperature to prevent undesirable compound formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the temperature is increased to enhance nicotine diffusion and release, then nicotine transfer yield improves, but formation of undesirable compounds increases and aerosol physical properties deteriorate

Engineering Contradiction:
Improvenicotine transfer yieldVSAvoidundesirable compound formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameter (pH) of the homogenized tobacco material by adding basic pH modifiers, which alters the nicotine release mechanism. This allows effective nicotine transfer at lower temperatures by modifying the chemical environment rather than relying solely on thermal diffusion, thus avoiding the formation of undesirable compounds associated with high-temperature heating.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If heating temperature is increased to improve nicotine release, then nicotine transfer yield increases, but aerosol temperature and particle size are adversely affected

Engineering Contradiction:
Improvenicotine transfer yieldVSAvoidaerosol temperature
Core Design Contradiction:
Manufacturing precisionVSTemperature

Solution Approach 1:

The patent modifies the chemical composition by incorporating basic pH modifiers into the homogenized tobacco material. This chemical modification enables nicotine release at lower heating temperatures by altering the protonation state and solubility of nicotine, thereby achieving satisfactory transfer yield without excessively increasing aerosol temperature and particle size.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional casting processes are used to produce homogenized tobacco material, then production is straightforward, but significant nicotine loss occurs during drying

Engineering Contradiction:
Improveproduction process simplicityVSAvoidnicotine loss during drying
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The patent changes the chemical parameter (pH) of the homogenized tobacco material used in conventional casting processes. By adding basic pH modifiers, nicotine is converted to its free base form which has lower solubility in the aqueous slurry, reducing nicotine loss during the drying step while maintaining the simplicity of the conventional casting manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a basic pH modifier increases the nicotine transfer yield to inhalable aerosols at lower temperatures, reducing nicotine loss during production and allowing for equivalent nicotine yields with potentially longer device operation and smaller battery requirements in electrically-operated systems.

Implementation Method 1

homogenised botanical material comprising plant material, an aerosol former and a basic pH modifier

Methodology Applied
Scientific EffectpH modification:

Implementation Method 2

an inhalable aerosol is formed by heating the aerosol-generating substrate to a relatively low temperature, for example a temperature of about 350° C

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 3

Migration of nicotine within homogenised tobacco material is limited by diffusion

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20210153541A1Homogenised botanical material comprising a basic ph modifier
Publication Date: 2021.05.27 PHILIP MORRIS PRODUCTS SA

AI summary

A homogenised botanical material is provided, including a particulate plant material, a content of which is greater than or equal to about 60% by weight, on a dry weight basis; an aerosol former; and a basic pH modifier having a solubility in water of less than or equal to about 0.1 g/100 mL water at 20° C. and 1 atm, the basic pH modifier including one or more basic inorganic salts selected from the group consisting of: alkaline earth metal hydrogen carbonates, alkaline earth metal hydroxides, and alkaline earth metal phosphates.