Honeycomb Catalyst Pore Diameter Back Pressure

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Solution Overview

Problem

Current catalyst technologies for purifying exhaust gas from internal combustion engines face challenges in efficiently trapping and combusting particulate matter, especially combustible carbon particulates, due to low contact efficiency and high back pressure issues, which lead to incomplete combustion and catalyst aging problems.

Innovation Solution

An open flow honeycomb substrate with an average pore diameter of 10-40 μm is used, coated with catalytically active components and heat-resistant inorganic substances in the form of protuberances to enhance trapping and combustion efficiency, allowing for continuous regeneration without the need for external heat treatment systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a filter substrate is used to trap particulate matter, then trapping efficiency is improved, but back pressure increases and engine load is inflicted

Engineering Contradiction:
Improveparticulate matter trapping efficiencyVSAvoidback pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent employs a porous substrate with controlled pore structure to trap particulate matter. The substrate contains pores with average diameter of 0.5-5 μm that can capture soot particles while maintaining adequate flow characteristics. The porous structure provides trapping function without requiring complete blockage of flow paths, thus balancing trapping efficiency with back pressure management.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies different functional coatings to different regions of the substrate. The inner surface of the substrate is coated with catalytic components for combustion, while the outer surface may have different properties. This local differentiation allows the substrate to simultaneously perform trapping, combustion, and flow management functions in different zones, optimizing overall performance without compromising any single function.

Inventive Principle:
Principle #3Local quality

2Reliability

If catalytic components are applied as very fine particles to maximize surface area, then catalytic activity is improved, but contact efficiency with SOOT decreases

Engineering Contradiction:
Improvecatalytic activityVSAvoidcontact efficiency with SOOT
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies catalytic components specifically to the inner surface of the substrate where SOOT particles accumulate during filtration. This localized application ensures that the catalyst is positioned exactly where it needs to contact the trapped particulates, maximizing contact efficiency while using moderate amounts of catalytic material. The coating thickness and distribution are controlled to optimize the interaction between catalyst and SOOT.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The substrate itself acts as an intermediary between the catalytic components and the SOOT particles. The porous structure of the substrate provides a matrix that holds the catalyst in close proximity to trapped particulates, facilitating contact without requiring the catalyst to be in direct contact with the gas stream. This intermediary role of the substrate enhances mass transfer and contact efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Temperature

If heat treatment methods are installed to raise exhaust gas temperature for catalyst regeneration, then regeneration capability is improved, but system complexity and cost increase

Engineering Contradiction:
Improveexhaust gas temperature for regenerationVSAvoidheat treatment system complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The catalyst system is designed to perform self-regeneration using the heat already present in the exhaust gas from the engine. The catalytic components promote combustion of trapped SOOT at temperatures that can be achieved during normal engine operation, particularly during high-load conditions when exhaust temperature is naturally elevated. This eliminates the need for external heating systems while maintaining regeneration capability.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes changes in exhaust gas temperature that occur naturally during engine operation cycles. During high-load operation, exhaust temperature increases naturally, providing the conditions needed for catalyst regeneration. The system leverages these periodic parameter changes in the exhaust environment to enable regeneration without additional active control systems or external heat sources.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If the catalyst traps and combusts SOOT at low temperatures, then combustion efficiency is improved, but sudden combustion leads to temperature spikes and catalyst aging

Engineering Contradiction:
Improvecombustion efficiency at low temperatureVSAvoidtemperature stability during combustion
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The porous substrate structure distributes the trapped SOOT throughout its volume, providing a large surface area for catalytic combustion. This distribution prevents localized accumulation of combustibles that could lead to sudden explosive combustion. The pores facilitate gradual oxidation and combustion reactions, releasing heat more uniformly and preventing temperature spikes that would damage the catalyst.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The catalytic components are applied in a controlled manner on the inner surface of the substrate, creating zones of catalytic activity distributed throughout the filter structure. This spatial distribution of catalyst ensures that combustion occurs at multiple locations simultaneously but at controlled rates, preventing runaway reactions. The local quality of the coating ensures adequate catalyst-SOOT contact while managing the heat release rate.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution improves the trapping and combustion efficiency of particulate matter, reducing back pressure and extending catalyst lifespan by ensuring continuous regeneration and high conversion rates across various engine operation conditions.

Implementation Method 1

an open flow honeycomb substrate with an average pore diameter of 10-40 μm is used

Methodology Applied
Scientific EffectPhysical filtration: Filter (physical)

Implementation Method 2

coated with catalytically active components and heat-resistant inorganic substances in the form of protuberances to enhance trapping and combustion efficiency

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

allowing for continuous regeneration without the need for external heat treatment systems

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS7740817B2Catalyst for purifying exhaust emission from internal combustion engine, method for preparation thereof and method for purifying exhaust emission from internal combustion engine
Publication Date: 2010.06.22 UMICORE SHOKUBAI JAPAN CO LTD

AI summary

A catalyst which efficiently removes particulate matter, SOF, sulfate, and SOOT and the like from the exhaust gas from such an internal combustion engine as a diesel engine without inducing a rise in the back pressure of the engine is provided. The catalyst for the purification of the exhaust gas of an internal combustion engine is formed by using an open flow honeycomb containing in the channel walls thereof such pores as possess an average diameter in the range of 10-40 μm.