Honeycomb Seal Diffusion Aluminide Coating Method

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Solution Overview

Problem

Honeycomb seals in gas turbines face oxidation and corrosion issues due to high temperatures, leading to a short lifespan, and existing slurry coating processes struggle with uniformity and complexity, especially when applied to internal and external surfaces with complicated geometries.

Innovation Solution

A method involving a gel aluminum-containing slurry with a halide activator and organic polymer binder is used to form a diffusion aluminide coating on honeycomb seals, which can be applied uniformly over a broad range of temperatures, followed by brazing to a substrate, ensuring a stable and durable aluminide coating with optional thermal barrier coating for enhanced protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional slurry coating processes are used on honeycomb seals, then coating can be applied to internal and external surfaces, but the coating uniformity and process complexity deteriorate when applied to surfaces with complicated geometries

Engineering Contradiction:
Improveability to coat internal and external surfacesVSAvoidcoating uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The invention changes the chemical parameters of the slurry composition by incorporating specific organic polymer binders and halide activators, which enable the coating material to flow uniformly into complex geometries and internal passages while maintaining consistent coating thickness through controlled chemical reactions during the diffusion process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The organic polymer binder acts as an intermediary carrier that transports the aluminum coating material uniformly across complex surfaces, allowing the slurry to penetrate internal passages and coat difficult-to-reach areas while maintaining coating uniformity through the binder's flow properties and adhesion characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If higher processing temperatures are used to form outward-type diffusion coatings, then oxidation and low-cycle fatigue resistance improve, but the processing complexity and energy consumption increase

Engineering Contradiction:
Improveoxidation and low-cycle fatigue resistanceVSAvoidprocessing temperature and energy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

The invention utilizes phase transitions of the halide activator and organic binder during controlled heating, where the halide activator volatilizes at specific temperature ranges to promote aluminum diffusion, and the organic binder decomposes and burns off, enabling the formation of outward-type diffusion coatings with improved oxidation and fatigue resistance through controlled phase changes rather than continuous high-temperature processing

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a uniformly thick diffusion aluminide coating that extends the lifespan of honeycomb seals by preventing oxidation and corrosion, with the ability to handle complex geometries and internal surfaces effectively, and allows for the production of both inward and outward-type coatings, improving oxidation and low-cycle fatigue resistance.

Implementation Method 1

react the activator with the metallic aluminum to form the halide vapor, react the halide vapor at the substrate surfaces to deposit aluminum on the surfaces of the seal

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

diffuse the deposited aluminum into the surfaces to form a diffusion aluminide coating

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

heating the component to a temperature sufficient to remove or burn off the binder

Methodology Applied
Scientific EffectDecomposition: Pyrolysis

Implementation Method 4

heating the braze material, seal substrate and coated cellular seal sufficiently to form a braze joint

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 5

brazing the coated cellular seal to a seal substrate to form the cellular seal member

Methodology Applied
Scientific EffectBrazing: Brazing

Implementation Method 6

aluminum-containing coatings form a protective aluminum oxide (alumina) scale or layer that inhibits corrosion and oxidation of the coating and the underlying substrate

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP2612951B1Method for making a honeycomb seal
Publication Date: 2020.10.28 GENERAL ELECTRIC CO
  • EP2612951B1 patent drawingFigure 1A~1B
  • EP2612951B1 patent drawingFigure 1C~2
  • EP2612951B1 patent drawingFigure 3

AI summary

A method (100) for making a cellular seal member for a turbine is disclosed. The method includes, in sequence, forming (110) a diffusion aluminide coating on a surface of a cellular seal to form a coated cellular seal. The method also includes brazing (120) the coated cellular seal (10) to a seal substrate (50).