Honeycomb Substrate Oxide Film Tapered Projections Adhesion

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Solution Overview

Problem

Existing catalyst support substrates for exhaust gas purification face challenges in achieving strong adhesion between the catalyst layer and the oxide film, requiring an adhesive layer that complicates processes and increases costs, and existing techniques do not effectively improve adhesion between the catalyst and the oxide film.

Innovation Solution

A honeycomb substrate with an oxide film having a high density of tapered oxide projections on its surface, formed through special heat treatment, allows for direct adhesion of the catalyst layer without an adhesive layer, enhancing the anchor effect and improving adhesion between the catalyst and the oxide film.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If an adhesive layer is introduced between the oxide film and zeolite layer to improve adhesion, then the adhesion strength is improved, but the device complexity and manufacturing cost increase

Engineering Contradiction:
Improveadhesion strengthVSAvoidstructure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent introduces an adhesive layer as an intermediary substance between the oxide film and zeolite layer. This adhesive layer acts as a mediator that chemically or physically bonds the two dissimilar materials together, enabling strong adhesion where direct bonding would fail due to incompatible surface properties and structures.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a multi-layer composite structure consisting of the oxide film, adhesive layer, and zeolite layer. Each layer has distinct properties optimized for its specific function, and the composite structure as a whole achieves superior adhesion performance that none of the individual layers could provide alone.

Inventive Principle:
Principle #40Composite materials

2Strength

If an adhesive layer is introduced between the oxide film and zeolite layer to improve adhesion, then the adhesion strength is improved, but the manufacturing cost increases

Engineering Contradiction:
Improveadhesion strengthVSAvoidmanufacturing cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The adhesive layer serves as a mediator that enables reliable bonding between the oxide film and zeolite layer, preventing catalyst separation and ensuring long-term durability of the catalytic converter, thereby justifying the additional manufacturing cost through improved product reliability and performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes parameters such as the thickness, composition, and surface properties of the adhesive layer to achieve the required adhesion strength while minimizing material costs and processing complexity, balancing performance requirements with manufacturing economy.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If the oxide film surface is made smooth to reduce manufacturing complexity, then the manufacturing process is simplified, but the adhesion between catalyst and oxide film deteriorates

Engineering Contradiction:
Improvesurface treatment complexityVSAvoidcatalyst adhesion
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The patent introduces surface roughness with curved features (peaks and valleys) on the oxide film surface. These curved surface features increase the effective surface area and create mechanical interlocking sites that enhance catalyst adhesion, demonstrating how surface curvature can improve bonding strength.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent creates a porous or rough surface structure on the oxide film with peaks and valleys. This porous morphology increases the surface area available for catalyst bonding and provides anchoring sites that mechanically interlock with the catalyst particles, thereby enhancing adhesion strength.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The enhanced adhesion between the catalyst layer and the oxide film improves the purification efficiency and reduces the complexity and cost of the process by eliminating the need for an adhesive layer.

Implementation Method 1

formed through special heat treatment

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentEP3590599B1Honeycomb substrate for catalyst support, and catalytic converter for exhaust gas purification
Publication Date: 2021.12.01 NIPPON STEEL CHEM & MATERIAL CO LTD
  • EP3590599B1 patent drawingFigure 1~2
  • EP3590599B1 patent drawingFigure 3~4
  • EP3590599B1 patent drawingFigure 5~6

AI summary

[Problem] The purpose of the invention is to improve adhesion of a catalyst layer and an oxide film in a honeycomb substrate for catalyst support. [Solution] A honeycomb substrate for catalyst support used in purification of exhaust gas is characterized by comprising a honeycomb body and an oxide film that is formed on the surface of the honeycomb body and that has α-alumina as a main component, and in that the oxide film includes multiple oxide projections that are formed to be dispersed on the film surface and that comprise a contracted shape in which the width becomes narrower near the honeycomb body, and the density of the projection formations on the film surface is 0.20 (pieces/µm2) - 3.00 (pieces/µm2).