Hose Rubber Composition Balancing Flame Retardancy and Wear

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Solution Overview

Problem

Hydraulic hoses used in construction and mining applications face issues with wear resistance and processability due to the exposure of reinforcing layers, leading to premature failure and potential leakage, despite the need for flame retardancy.

Innovation Solution

A rubber composition combining chloroprene rubber, butadiene rubber, sulfur, and aromatic oil, with specific ratios and the inclusion of a silane coupling agent, carbon black, and silica, to enhance flame retardancy, wear resistance, and compression set.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If chloroprene rubber and silica are blended to improve flame retardancy, then flame retardancy is improved, but scorch time becomes short and processability deteriorates

Engineering Contradiction:
Improveflame retardancyVSAvoidprocessability
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent optimizes the content of chloroprene rubber to 60-75 mass% and controls sulfur content at 0.2-2.5 parts by mass per 100 parts by mass of rubber component, along with adding aromatic oil (10 parts by mass or more per 100 parts by mass of rubber component) to adjust the curing characteristics and extend scorch time, thereby improving processability while maintaining flame retardancy

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite rubber composition containing chloroprene rubber, butadiene rubber (25-40 mass%), silica, carbon black, and aromatic oil, where the combination of these materials provides both flame retardancy and improved processability through synergistic effects

Inventive Principle:
Principle #40Composite materials

2Strength

If silane coupling agent is added to improve wear resistance, then wear resistance is improved, but compression set becomes poor and durability deteriorates

Engineering Contradiction:
Improvewear resistanceVSAvoidcompression set
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent precisely controls the sulfur content at 0.2-2.5 parts by mass per 100 parts by mass of rubber component and limits silane coupling agent to 0-2 mass% based on total rubber component mass, while adding aromatic oil to optimize the curing characteristics, achieving both wear resistance and good compression set

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If rubber composition is optimized for flame retardancy, then flame retardancy is improved, but scorch time becomes short leading to poor processing stability

Engineering Contradiction:
Improveflame retardancyVSAvoidprocessing stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent adjusts the rubber composition by controlling chloroprene rubber at 60-75 mass%, adding butadiene rubber at 25-40 mass%, and incorporating aromatic oil at 10 parts by mass or more per 100 parts by mass of rubber component, which modifies the curing characteristics to extend scorch time and improve processing stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses aromatic oil as an intermediary substance that mediates between the flame retardant properties of chloroprene rubber and the processing requirements, extending scorch time and improving processing stability without compromising flame retardancy

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The rubber composition improves processability, flame retardancy, wear resistance, and sealability, reducing the likelihood of premature hose failure and leakage while maintaining safety standards.

Implementation Method 1

it is effective to blend a silane coupling agent into a rubber composition in order to improve wear resistance

Methodology Applied
Scientific EffectSilane coupling: Chemical Bonding

Implementation Method 2

it is effective to blend chloroprene rubber (CR) and silica into a rubber composition in order to improve flame retardancy

Methodology Applied
Scientific EffectFlame retardancy: Combustion

Implementation Method 3

a rubber composition for a hose including a rubber component, carbon black, and a plasticizer component

Methodology Applied
Scientific EffectVulcanization: Chemical Bonding

Implementation Method 4

the plasticizer component includes a flame-retardant plasticizer, and 2 parts by mass or more of the flame-retardant plasticizer is contained per 100 parts by mass of the rubber component

Methodology Applied
Scientific EffectPlasticization: Solvation

Data Source

PatentUS20240317979A1Rubber composition for hose, and hose
Publication Date: 2024.09.26 THE YOKOHAMA RUBBER CO LTD
  • US20240317979A1 patent drawing
  • US20240317979A1 patent drawing

AI summary

A rubber composition for a hose including a rubber component containing chloroprene rubber and butadiene rubber, sulfur, and an aromatic oil. With respect to the total mass of the rubber component: the chloroprene rubber being contained in an amount of 60 mass % or more and less than 75 mass %; and the butadiene rubber being contained in an amount of more than 25 mass % and 40 mass % or less. Relative to 100 parts by mass of the rubber component: the sulfur being contained in an amount of more than 0.2 parts by mass and less than 2.5 parts by mass; and the aromatic oil being contained in an amount of 10 parts by mass or more. An optional silane coupling agent may be contained in an amount of from 0 to 2 mass % with respect to the total mass of the rubber component.