Organic Optoelectronic Host Composition Balancing Carrier Transport

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Solution Overview

Problem

Current organic light emitting diodes (OLEDs) face challenges in achieving high efficiency and long life-span due to limitations in hole and electron mobility and electrochemical stability, particularly when used in large-size flat panel displays.

Innovation Solution

A composition for an organic optoelectronic device is developed, comprising a combination of a first host compound with strong hole transport characteristics and a second host compound with strong electron transport characteristics, along with a dopant, to balance carrier transport and emission, thereby enhancing luminous efficiency and life-span.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single organic material is used in the organic layer, then the device structure is simple, but hole and electron mobility cannot be simultaneously increased and electrochemical stability is limited

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidorganic layer composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite organic materials comprising multiple components with different functionalities. Specifically, it combines hole transport materials (HTM), electron transport materials (ETM), and optionally luminescent materials or charge generation materials in defined weight ratios (HTM:ETM = 1:4 to 4:1, with optimal 1:1). This composite approach enables simultaneous improvement of hole and electron mobility while enhancing electrochemical stability through synergistic interactions between components, resolving the contradiction between material complexity and performance reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent assigns different functional properties to different components within the organic layer. Hole transport materials provide predominant hole transport capability, electron transport materials provide predominant electron transport capability, and their combination creates localized functional zones that collectively achieve balanced carrier transport and improved electrochemical stability without requiring complete structural redesign.

Inventive Principle:
Principle #3Local quality

2Productivity

If conventional organic materials are used, then the material selection is straightforward, but luminous efficiency and life-span are insufficient for large-size flat panel displays

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddevice life-span
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

The patent systematically optimizes critical parameters including the weight ratio of HTM to ETM (1:4 to 4:1, optimal 1:1), molecular structure characteristics (HOMO/LUMO energy levels, triplet energy levels), and material composition ratios. These parameter changes enable simultaneous enhancement of luminous efficiency (through optimized exciton generation and carrier recombination) and device life-span (through improved electrochemical stability and reduced degradation), meeting the demanding requirements for large-size flat panel displays.

Inventive Principle:
Principle #35Parameter changes

3Speed

If the organic layer uses materials with high carrier mobility, then charge transport is improved, but electrochemical stability deteriorates

Engineering Contradiction:
Improvecarrier mobilityVSAvoidelectrochemical stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent creates a composite organic layer where high-mobility materials are combined with electrochemically stable materials in optimized ratios. The HTM and ETM components are selected and proportioned to balance carrier mobility enhancement with electrochemical stability maintenance, allowing the system to achieve high charge transport rates while resisting degradation from electrochemical reactions during device operation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition significantly improves luminous efficiency and life-span of OLEDs by balancing carrier transport, reducing driving voltage, and extending the device's operational life, as demonstrated in various organic light emitting diode examples.

Implementation Method 1

a first host compound having strong hole transport characteristics

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 2

a second host compound having strong electron transport characteristics

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

an organic light emitting diode is a device converting electrical energy into light by applying current to an organic light emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10319921B2Composition for organic optoelectronic device and organic optoelectronic device and display device
Publication Date: 2019.06.11 SAMSUNG SDI CO LTD
  • US10319921B2 patent drawing
  • US10319921B2 patent drawing
  • US10319921B2 patent drawing

AI summary

Disclosed are a composition for an organic optoelectronic device includes at least one of a first host compound represented by a combination of Chemical Formula 1 and Chemical Formula 2, and at least one of a second host compound represented by a combination of Chemical Formula 3 and Chemical Formula 4, and an organic optoelectronic device including the same, and a display device.Details of Chemical Formula 1 to 4 are the same as described in the detailed description.