Host-Guest LCM Composition Sealing Sub-Micron Wellbore Fractures

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Solution Overview

Problem

Traditional lost circulation materials (LCMs) are ineffective in sealing sub-micron cracks and fractures in wellbores, leading to continued fluid loss due to their inability to plug smaller openings.

Innovation Solution

A host-guest LCM composition is developed, comprising cyclic molecules and linear polymer chains in an aqueous solution, forming a host-guest structure that can fit into and plug both sub-micron and larger fractures, using polyethylene glycols, polypropylene glycols, and polydimethylsiloxanes with alpha, beta, or gamma cyclodextrins, which create a flexible and stable plug.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional lost circulation materials (granular, fibrous, flaky, or granular) are used to seal cracks and fractures, then they can plug moderate to large cracks and fractures, but they cannot adequately plug sub-micron sized cracks and fractures

Engineering Contradiction:
Improvesealing effectivenessVSAvoidcrack plugging capability
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The lost circulation material is segmented into two distinct components: a host component (natural or synthetic polymer, ceramic, or metal) and a guest component (particulate material with average particle size of 0.1 to 10 microns). This segmentation allows the host to provide structural framework while the fine guest particles fill sub-micron cracks, achieving sealing effectiveness across all crack sizes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite materials combining host and guest components with complementary properties. The host material (polymer, ceramic, or metal) provides structural integrity and crack plugging, while the guest particulate material (0.1 to 10 microns) fills sub-micron fractures. This composite approach enables simultaneous sealing of both large and sub-micron cracks, resolving the contradiction between sealing effectiveness and crack plugging capability.

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If larger particulate materials are used to plug fractures, then they can seal larger cracks, but they cannot penetrate and seal sub-micron fractures

Engineering Contradiction:
Improvefracture sealing areaVSAvoidsub-micron crack plugging
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The sealing system is segmented into host and guest components with different size ranges. The host provides the structural framework for large fracture sealing, while the guest component (0.1 to 10 microns) specifically targets sub-micron cracks. This segmentation enables the system to address both large and sub-micron fractures simultaneously without compromise.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the lost circulation material have different qualities: the host component addresses large fracture areas, while the fine guest particles (0.1 to 10 microns) concentrate on sub-micron crack sealing. This local differentiation of material properties allows simultaneous effective sealing across all fracture sizes, resolving the contradiction between sealing area and sub-micron plugging capability.

Inventive Principle:
Principle #3Local quality

3Device complexity

If single-component LCM materials are used, then the formulation is simple, but they cannot simultaneously plug both large and sub-micron fractures

Engineering Contradiction:
Improvematerial formulationVSAvoidcomprehensive crack sealing
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The invention merges two functional components into a single lost circulation material system: the host component (polymer, ceramic, or metal) that seals large fractures and the guest component (particulate material, 0.1 to 10 microns) that seals sub-micron cracks. This merging enables comprehensive sealing of all crack sizes while maintaining a unified material formulation that can be applied together, balancing formulation simplicity with comprehensive sealing capability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The combined host-guest LCM system provides multi-functionality: the host component seals large fractures and provides structural support, while the guest component seals sub-micron cracks. This universal formulation simultaneously performs multiple sealing functions across different crack sizes, achieving comprehensive crack sealing without requiring separate materials for different fracture types.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The LCM composition significantly reduces filtration loss through the wellbore wall by effectively sealing both sub-micron and larger fractures, enhancing the stability of the wellbore and reducing the risk of collapse or sloughing.

Implementation Method 1

one or more cyclic molecules form a host-guest structure around the one or more linear polymer chains utilizing van der Waals forces

Methodology Applied
Scientific EffectVan der Waals forces: Van der Waals Force

Data Source

PatentUS20240067857A1Host-guest lost-circulation materials for sealing lost circulation zones in wellbores
Publication Date: 2024.02.29 SAUDI ARABIAN OIL CO
  • US20240067857A1 patent drawing
  • US20240067857A1 patent drawing
  • US20240067857A1 patent drawing

AI summary

In accordance with one or more embodiments of the present disclosure, a host-guest lost circulation material (LCM) composition for sealing lost circulation zones in wellbores includes an aqueous solution; one or more linear polymer chains, the linear polymer chains comprising polyethylene glycols (PEG) with molecular weights greater than 2500 g/mol, polypropylene glycols (PPG), polydimethylsiloxanes (PDMS), or combinations thereof; and one or more cyclic molecules comprising alpha cyclodextrin, beta cyclodextrin, gamma cyclodextrin, or combinations thereof, and wherein the one or more cyclic molecules form a host-guest structure around the one or more linear polymer chains utilizing van der Waals forces.