Host Material Combination for Phosphorescent OLED Efficiency

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Solution Overview

Problem

The development of stable and efficient host materials for phosphorescent organic electric elements is hindered by challenges in controlling energy transfer from host to dopant materials, affecting charge balance, efficiency, and lifespan.

Innovation Solution

A combination of a first and second host material is used in the phosphorescent emitting layer, with specific compounds represented by Formulas 1 and 2, to reduce energy barriers and maximize charge balance, enhancing efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single host material is used in the phosphorescent emitting layer, then the device structure is simple, but the efficiency and lifespan are limited due to insufficient control over energy transfer and charge balance

Engineering Contradiction:
ImprovelifespanVSAvoidhost material structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite host material system consisting of a first host material (Formula 1) and a second host material (Formula 2) in the phosphorescent emitting layer. This composite structure enables simultaneous optimization of energy transfer pathways and charge balance, achieving extended device lifespan and enhanced efficiency while maintaining manageable structural complexity through defined molecular frameworks.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If energy transfer from host to dopant is optimized, then luminous efficiency increases, but control over charge balance and energy barriers becomes more difficult

Engineering Contradiction:
Improveluminous efficiencyVSAvoidenergy transfer control
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes by systematically adjusting the molecular structures of the host materials (Formulas 1 and 2) to optimize energy transfer parameters. By modifying structural parameters such as heteroatom types, ring configurations, and substituent groups, the invention achieves controlled energy transfer to dopant materials while maintaining charge balance, thereby enhancing luminous efficiency with manageable control complexity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the HOMO level of the host material is controlled to maximize charge balance, then efficiency and lifespan improve, but material development and selection become more challenging

Engineering Contradiction:
Improvecharge balanceVSAvoidmaterial development
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies segmentation by dividing the host material into two distinct components (first host material of Formula 1 and second host material of Formula 2), each contributing specific functions to the emitting layer. This segmentation allows independent optimization of HOMO levels and charge balance properties, making material development more systematic and manageable while achieving superior overall performance.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in high luminous efficiency and extended lifespan of organic electric elements with reduced driving voltage.

Implementation Method 1

many studies have been carried out to identify the energy transfer method from the host material to the dopant material

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

In a phosphorescent organic electric element using a phosphorescent dopant material

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 3

organic light emitting phenomenon refers to a phenomenon that converts electric energy into light energy by using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11856843B2Compound for organic electric element, organic electric element using the same, and electronic device therefor
Publication Date: 2023.12.26 DUK SAN NEOLUX
  • US11856843B2 patent drawing
  • US11856843B2 patent drawing
  • US11856843B2 patent drawing

AI summary

Provided is a novel mixture capable of improving luminous efficiency, stability, and lifespan of an element, an organic electric element using the same, and an electronic device therefor.