Organic Electroluminescent Host Material Composite for Efficiency and Lifetime

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Solution Overview

Problem

Existing organic electroluminescent devices, particularly those using triplet emission (phosphorescence), face challenges in efficiency, operating voltage, and service life, despite advancements in host and matrix materials.

Innovation Solution

A combination of specific electron-transporting and hole-transporting host materials, represented by compounds of formulas (1) and (2), is used in the light-emitting layer of organic electroluminescent devices, enhancing device properties such as service life, efficiency, and operating voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If phosphorescent emitters are used in organic electroluminescent devices, then energy efficiency is improved, but service life and operating voltage performance deteriorate

Engineering Contradiction:
Improveenergy efficiencyVSAvoidservice life
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent employs a composite host material system consisting of two distinct components: a first host material (compounds of formula (1)) that provides electron transport and triplet energy, and a second host material (compounds of formula (2)) that provides hole transport. This composite approach allows the device to simultaneously achieve high energy efficiency through phosphorescent emission while improving service life by distributing the operational stress and enhancing stability through the synergistic interaction of the two host materials, thereby resolving the contradiction between efficiency and reliability.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If phosphorescent emitters are used in organic electroluminescent devices, then energy efficiency is improved, but operating voltage performance deteriorates

Engineering Contradiction:
Improveenergy efficiencyVSAvoidoperating voltage
Core Design Contradiction:
Loss of energyVSPower

Solution Approach 1:

The patent employs a composite host material system consisting of two distinct components: a first host material (compounds of formula (1)) that provides electron transport and triplet energy, and a second host material (compounds of formula (2)) that provides hole transport. This composite approach allows the device to simultaneously achieve high energy efficiency through phosphorescent emission while improving service life by distributing the operational stress and enhancing stability through the synergistic interaction of the two host materials, thereby resolving the contradiction between efficiency and reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these host material combinations in the light-emitting layer improves the service life and maintains or enhances efficiency and operating voltage of organic electroluminescent devices, particularly when used with phosphorescent emitters at specific concentrations.

Implementation Method 1

Organic electroluminescent device comprising a light-emitting layer, wherein the light-emitting layer contains two host materials

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

thereof, in particular with regard to lifetime, as well as to provide the corresponding electroluminescent device... especially in the presence of a light-emitting component in the emission layer, especially in combination with emitters of formula (5)

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentEP4055641B1Organic electroluminescent apparatus
Publication Date: 2023.07.19 MERCK PATENT GMBH
  • EP4055641B1 patent drawing
  • EP4055641B1 patent drawing
  • EP4055641B1 patent drawing

AI summary

The present invention relates to an organic electroluminescent apparatus containing a mixture that comprises an electron-transporting host material and a hole-transporting host material, as well as to a formulation containing a mixture of the host materials and to a mixture containing the host materials. The electron-transporting host material corresponds to a compound of formula (1) from the class of compounds containing a bispirofluorenyl unit.