Organic Electroluminescent Host Materials for Extended Lifetime

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving long lifetime and high efficiency, particularly in middle to large-sized panels, due to limitations in luminous efficiency, thermal stability, and electrochemical stability of conventional light-emitting materials.

Innovation Solution

A new organic electroluminescent compound is introduced, represented by specific formulas, which can be used as host materials in combination with other compounds to enhance the performance and longevity of organic electroluminescent devices, comprising a combination of specific arylene and heteroarylene linkages, and heteroaryl substituents to improve thermal and electrochemical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional phosphorescent materials are used in OLED, then luminous efficiency is improved, but lifetime is shortened

Engineering Contradiction:
Improveluminous efficiencyVSAvoidlifetime
Core Design Contradiction:
Loss of energyVSDuration of action of stationary object

Solution Approach 1:

The patent changes the molecular weight parameter of the host material to greater than 350 g/mol, which fundamentally alters the material properties to achieve both high luminous efficiency and extended lifetime, resolving the trade-off between these two parameters

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite host materials comprising multiple compounds with specific molecular weights and structures, creating a synergistic system that maintains high luminous efficiency while significantly extending device lifetime through improved thermal and electrochemical stability

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If host material with high molecular weight is used, then thermal stability is improved, but ease of deposition is worsened

Engineering Contradiction:
Improvethermal stabilityVSAvoidease of deposition
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent optimizes the molecular weight parameter to a specific range (greater than 350 g/mol) that balances thermal stability requirements with deposition feasibility, ensuring materials can be effectively deposited while maintaining high thermal stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and molecular structures at particular positions within the host material molecules, creating local regions with optimized properties that facilitate deposition while the overall molecular weight ensures thermal stability

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional host materials are used, then ease of forming thin film is improved, but electrochemical stability is worsened

Engineering Contradiction:
Improveease of forming thin filmVSAvoidelectrochemical stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent uses composite host material systems that combine compounds with complementary properties, where the overall system achieves high electrochemical stability while maintaining ease of thin film formation through the协同 effects of the component materials

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the electrochemical parameters of host materials by selecting compounds with specific HOMO-LUMO energy levels and redox potentials, ensuring high electrochemical stability while maintaining processability and ease of thin film formation

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20240343974A1Organic electroluminescent compound, a plurality of host materials and organic electroluminescent device comprising the same
Publication Date: 2024.10.17 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US20240343974A1 patent drawing
  • US20240343974A1 patent drawing
  • US20240343974A1 patent drawing

AI summary

The present disclosure relates to an organic electroluminescent compound represented by formula 1, a plurality of host materials comprising a specific combination of compounds, and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound or the specific combination of compounds according to the present disclosure as host materials, it is possible to provide an organic electroluminescent device with a longer lifetime property compared to conventional organic electroluminescent devices.