Hot Fill Closure Deformation Resistance via HDPE Composition

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Solution Overview

Problem

Existing hot filling processes face challenges in finding materials for closures that provide heat resistance, good sealing properties, and resistance to deformation and cracking, especially due to the complex geometries and small dimensions of plastic closures, which are difficult to test using standard methods.

Innovation Solution

The use of high density unimodal polyethylene compositions with specific density, melt index, weight average molecular weight, and molecular weight distribution, along with a compressive strain model to evaluate deformation properties, allowing for the selection of suitable polymer compositions for hot fill and aseptic fill applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If standard compression molded specimens or plaques are used for creep testing, then standardized test procedures can be employed, but the final polymer morphology in molded closures is not represented

Engineering Contradiction:
Improveease of testingVSAvoidaccuracy of deformation properties
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The patent creates a replica or model of the actual closure geometry using the same polymer material. This model closure is then subjected to creep testing, allowing the test to replicate the actual stress conditions and morphology of the finished product while maintaining standardized testing procedures. The model serves as a copy that preserves the critical geometric and material properties of the actual closure.

Inventive Principle:
Principle #26Copying

2Ease of manufacture

If complex geometry closures are tested using standard methods, then standardized procedures can be used, but the testing becomes difficult due to complex geometries and small dimensions

Engineering Contradiction:
Improveease of testingVSAvoiddifficulty of testing
Core Design Contradiction:
Ease of manufactureVSDifficulty of detecting and measuring

Solution Approach 1:

The patent creates a simplified model or replica of the complex closure geometry that retains the essential stress-bearing features while being easier to instrument and measure. This model closure allows for the application of standardized testing procedures while avoiding the measurement difficulties associated with the full complexity of the actual closure geometry and small dimensions.

Inventive Principle:
Principle #26Copying

3Reliability

If high density polyethylene is used for closures, then good sealing properties are achieved, but resistance to deformation during hot/cold cycles is insufficient

Engineering Contradiction:
Improvesealing propertiesVSAvoidresistance to deformation
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent modifies the polymer composition parameters by incorporating specific additives, fillers, or cross-linking agents into the high density polyethylene base material. These parameter changes enhance the material's dimensional stability and resistance to thermal deformation while preserving its excellent sealing properties. The composition is tuned to achieve both sealing reliability and deformation resistance simultaneously.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system where high density polyethylene is combined with other materials such as cross-linking agents, fillers, or reinforcing fibers. This composite approach leverages the sealing properties of HDPE while adding the deformation resistance provided by the complementary materials, achieving both required properties in a single closure component.

Inventive Principle:
Principle #40Composite materials

4Reliability

If closures are exposed to hot liquid for sterilization, then microbial growth is prevented, but the closure may deform or crack

Engineering Contradiction:
Improvesterilization effectivenessVSAvoidresistance to cracking
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent modifies the polymer's thermal properties through composition adjustments, adding heat-resistant additives or cross-linking agents that raise the glass transition temperature and improve thermal stability. These parameter changes allow the closure to withstand the high temperatures required for sterilization without deforming or cracking, while still achieving effective microbial elimination.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10071895B2Hot fill process with closures made from high density unimodal polyethylene
Publication Date: 2018.09.11 NOVA CHEM (INT) SA
  • US10071895B2 patent drawing
  • US10071895B2 patent drawing
  • US10071895B2 patent drawing

AI summary

High density (density ≥0.945 g/cm3) unimodal polyethylene compositions for use in hot-fill closures and processes.