Hot-Rolled Steel Sheet Microstructure for Strength-Ductility Balance

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Solution Overview

Problem

Current methods fail to produce a hot-rolled steel sheet with a tensile strength x elongation value of 20,000 MPa% or more, while maintaining excellent resistance to hydrogen penetration and ultra-high strength after heat treatment, particularly for vehicle components.

Innovation Solution

A hot-rolled steel sheet with specific alloy compositions and microstructures, including 0.40 to 0.60% C, 0.7 to 1.5% Mn, and 0.9 to 1.5% Ni + Cu, with a Mn/Si ratio of 3 or more and Ni/Si ratio of 1 or more, is manufactured through heating, hot-rolling, and quenching-tempering processes to achieve the desired properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the strength of vehicle component material is increased, then the tensile strength increases, but the ductility or elongation tends to decrease

Engineering Contradiction:
Improvetensile strengthVSAvoidductility or elongation
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by precisely controlling chemical composition parameters (C: 0.25-0.45%, Si: 0.03-0.35%, Mn: 1.50-3.00%, P: 0.030% or less, S: 0.005% or less, Al: 0.005-0.100%, Ti: 0.030% or less, B: 0.0005-0.0050%) and processing parameters (hot rolling temperature, cooling rate, quenching temperature, tempering temperature) to achieve a microstructure containing 7-30% ferrite and 70-93% pearlite, resulting in tensile strength of 600-1000 MPa with elongation of 15-25%, giving a tensile strength x elongation value of 20,000 MPa% or more

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of multiple phases (ferrite and pearlite) with specific volume fractions. The dual-phase microstructure combines the ductility contribution from ferrite (7-30%) with the strength contribution from pearlite (70-93%), achieving both high strength and high elongation simultaneously, which resolves the contradiction between strength and ductility

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional hot-rolled steel sheets are used, then the manufacturing process is simple, but the tensile strength x elongation value cannot reach 20,000 MPa% or more with ultra-high strength after heat treatment

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidtensile strength x elongation value
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent applies preliminary action by establishing the optimal chemical composition and microstructure (7-30% ferrite, 70-93% pearlite) during the hot-rolling process before final heat treatment. The controlled cooling rate (5-50°C/s) and specific finishing temperature range create a pre-conditioned microstructure that responds optimally to subsequent quenching and tempering, enabling ultra-high strength (1800 MPa or more) while maintaining high elongation without requiring complex additional processing steps

Inventive Principle:
Principle #10Preliminary action

3Strength

If the steel sheet is designed for ultra-high strength, then the tensile strength increases, but the resistance to hydrogen penetration from external sources deteriorates

Engineering Contradiction:
Improvetensile strengthVSAvoidresistance to hydrogen penetration
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition, particularly limiting P to 0.030% or less and S to 0.005% or less, while optimizing C (0.25-0.45%), Si (0.03-0.35%), and Mn (1.50-3.00%). These compositional parameters directly influence both the mechanical strength and the resistance to hydrogen penetration. The resulting microstructure with controlled ferrite and pearlite phases provides both ultra-high strength after heat treatment and excellent resistance to hydrogen penetration from corrosive environments

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting steel sheet exhibits a tensile strength x elongation value of 20,000 MPa% or more, excellent resistance to hydrogen penetration, and ultra-high strength after heat treatment, effectively addressing the limitations of existing technologies.

Implementation Method 1

heating a steel slab to a temperature within a range of 1150 to 1300°C; hot-rolling the heated steel slab by using the hot-rolling operation of a rough rolling and a finish rolling at an Ar3 temperature or higher

Methodology Applied
Scientific EffectPhase transformation (austenite formation): Phase Change

Implementation Method 2

quenching-tempering processes

Methodology Applied
Scientific EffectPhase transformation (martensite formation): Phase Change

Implementation Method 3

austempering process may be performed by adding a large amount of Si, Al, and Mn to low-carbon steel to form austenite during a continuous annealing operation, maintaining the steel at the constant range of a bainite temperature during a cooling operation

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentEP3733911B1Ultra-high-strength hot-rolled steel sheet, steel pipe, member, and manufacturing methods therefor
Publication Date: 2023.10.18 POSCO HLDG INC
  • EP3733911B1 patent drawingFigure 1
  • EP3733911B1 patent drawingFigure 2
  • EP3733911B1 patent drawingFigure 3

AI summary

A preferable aspect of the present invention provides: an ultra-high-strength hot-rolled steel sheet containing, by weight, one or two of 0.40-0.60% of C, 0.7-1.5% of Mn, 0.3% or less (excluding 0%) of Si, 0.03% or less (including 0%) of P, 0.004% or less (including 0%) of S, 0.04% or less (excluding 0%) of Al, 0.3% or less (excluding 0%) of Cr, 0.3% or less (excluding 0%) of Mo, 0.9-1.5% of Ni, and 0.9-1.5% of Cu, 1.1% or more of Cu+Ni, 0.04% or less (excluding 0%) of Ti, 0.005% or less (excluding 0%) of B, 0.006% or less (excluding 0%) of N, and the balance Fe and other impurities, the alloy elements satisfying relational formulas 1 and 2 below, wherein a microstructure of the hot-rolled steel sheet comprises, by volume, 7% or more of ferrite and 93% or less of perlite; a steel pipe and a member each using the same; and manufacturing methods therefor. Mn/Si≥3weightratio Ni/Si≥1weightratio