Humidified CO2 Electrolysis for High-Efficiency Carbon Monoxide Production

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Solution Overview

Problem

Existing electrolysis processes for converting carbon dioxide into carbon monoxide have low efficiency, which hinders the effective production of carbon monoxide for use in various chemical processes and energy applications.

Innovation Solution

A method involving the humidification of an educt gas containing carbon dioxide before electrolysis, followed by electrolysis in a high-temperature electrolytic cell with specific electrode configurations, to enhance the efficiency of carbon monoxide production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electrolysis processes are used to convert carbon dioxide into carbon monoxide, then carbon monoxide can be produced, but the efficiency of the process is low

Engineering Contradiction:
Improvecarbon monoxide production efficiencyVSAvoidenergy efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent applies parameter changes by humidifying the educt gas before electrolysis and operating at elevated temperatures (600-900°C). These parameter modifications optimize the electrolysis conditions, improving both the efficiency of carbon monoxide production and energy utilization. The humidification prevents electrode degradation and enhances reaction kinetics, while the temperature control balances reaction rate with energy consumption.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If carbon dioxide is converted into carbon monoxide by supplying energy, then the carbon monoxide can be used for more applications, but the process requires significant energy input

Engineering Contradiction:
Improveapplication range of carbon productVSAvoidenergy input for conversion
Core Design Contradiction:
Adaptability or versatilityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes energy input by controlling electrolysis parameters including temperature (600-900°C), gas composition, and current density. These parameter adjustments ensure efficient energy utilization while producing carbon monoxide suitable for multiple applications such as synthesis gas production and chemical synthesis.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts carbon dioxide, a harmful greenhouse gas, into valuable carbon monoxide through electrolysis. This transforms a climate-damaging substance into a useful chemical feedstock, simultaneously addressing environmental concerns and providing industrial utility.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If high-temperature electrolysis is used to improve carbon monoxide production efficiency, then productivity increases, but the device complexity and operational requirements increase

Engineering Contradiction:
Improvecarbon monoxide production rateVSAvoidelectrolytic cell configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs parameter changes including temperature control (600-900°C), humidification of educt gas, and specific electrode material selection. These changes enhance productivity while managing device complexity through systematic optimization of operational parameters rather than complex structural modifications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed method significantly improves the efficiency of carbon monoxide production by optimizing the electrolysis process through humidification and specific electrode configurations, thereby supporting the energy transition and reducing climate-damaging emissions.

Implementation Method 1

electrolyzing the humidified educt gas supplied according to step b) in the electrolytic cell such that the carbon monoxide is obtained

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

humidifying an educt gas containing carbon dioxide with water

Methodology Applied
Scientific EffectHumidification: Evaporation

Data Source

PatentUS12281397B2Producing carbon monoxide
Publication Date: 2025.04.22 FORSCHUNGSZENTRUM JULICH GMBH
  • US12281397B2 patent drawing
  • US12281397B2 patent drawing

AI summary

The invention relates to a method for producing carbon monoxide, comprising the following steps:a) humidifying an educt gas containing carbon dioxide with water,b) supplying the humidified educt gas from step a) into an electrolytic cell (1), andc) electrolyzing the humidified educt gas supplied according to step b) in the electrolytic cell (1) such that the carbon monoxide is obtained.With the described method and with the described device (12), carbon monoxide can be produced via CO2 electrolysis with particularly high efficiency. This is achieved with the educt gas containing carbon dioxide being humidified before the electrolysis.