Transparent Conductors Fabricated via Humidity-Controlled Spray Coating

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Solution Overview

Problem

Conventional methods for fabricating transparent conductors face challenges such as high costs, complex equipment requirements, poor productivity, and issues with spectral uniformity, adhesion, and brittleness, particularly with metal oxide-based films, while alternative conductive components like silver nanowires offer superior durability but require precise processing conditions for optimal transparency and conductivity.

Innovation Solution

The method involves forming a dispersion of conductive components like silver nanowires with a solvent and applying it to a substrate in a controlled humidity environment, typically between 50% to 70% atmospheric humidity, to control the morphology and conductivity of the resulting transparent conductor, allowing for enhanced transparency and conductivity without expensive equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal oxide-based transparent conductive films are fabricated using conventional dry processes, then good transparency and conductivity are achieved, but expensive materials and complicated apparatuses are required resulting in poor productivity

Engineering Contradiction:
Improvetransparency and conductivityVSAvoidproductivity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent replaces complex mechanical vacuum deposition systems with a simple spray coating process. The dispersion is applied using a spray head that can be moved along the substrate, eliminating the need for expensive vacuum chambers and sputtering equipment while achieving comparable transparent conductor quality

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses inexpensive organic solvents and simple spray coating materials instead of expensive metal oxide powders and complex deposition equipment. The spray head and basic coating apparatus are much cheaper than conventional PVD/CVD systems, enabling high productivity at low cost

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Ease of manufacture

If metal oxide-based transparent conductive coatings are fabricated using conventional wet processes, then simpler fabrication is achieved, but supply restriction, lack of spectral uniformity, poor adhesion, and brittleness occur

Engineering Contradiction:
Improveease of manufactureVSAvoidadhesion and brittleness
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes the solvent composition and humidity parameters during the spray coating process to control the morphology and adhesion of the transparent conductor. By controlling evaporation rate and ambient humidity, the process achieves both ease of manufacture and reliable adhesion without brittleness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite dispersions containing conductive components (such as silver nanowires or metal oxide nanoparticles) suspended in organic solvents with specific additives. This composite approach combines the simplicity of wet processing with improved adhesion and mechanical properties

Inventive Principle:
Principle #40Composite materials

3Strength

If transparent conductors are fabricated using conductive components like silver nanowires and carbon nanotubes, then mechanical durability is improved, but transparency and conductivity depend on the fabrication process

Engineering Contradiction:
Improvemechanical durabilityVSAvoidtransparency and conductivity control
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent precisely controls ambient humidity and solvent evaporation rate during the spray coating process to optimize the network formation of conductive components. By adjusting these parameters, the process achieves both mechanical durability and controlled transparency/conductivity characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs feedback control by monitoring the humidity and evaporation conditions during coating, and adjusting process parameters accordingly to achieve consistent transparency and conductivity while maintaining mechanical durability of the conductive component network

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of transparent conductors with adjustable conductivity and morphology based on humidity, achieving high light transmittance and surface resistivity, suitable for various applications like flexible displays, while reducing production costs and complexity.

Implementation Method 1

The solvent is caused to at least partially evaporate such that the plurality of conductive components remains overlying the substrate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

applying the dispersion to a substrate in an environment having an atmospheric humidity that is based on a selected surface resistivity of the transparent conductor

Methodology Applied
Scientific EffectHumidity control:

Data Source

PatentUS7727578B2Transparent conductors and methods for fabricating transparent conductors
Publication Date: 2010.06.01 SOLSTICE ADVANCED MATERIALS US INC
  • US7727578B2 patent drawing
  • US7727578B2 patent drawing
  • US7727578B2 patent drawing

AI summary

Transparent conductors and methods for fabricating transparent conductors are provided. In one exemplary embodiment, a method for fabricating a transparent conductor comprises forming a dispersion comprising a plurality of conductive components and a solvent, applying the dispersion to a substrate in an environment having a predetermined atmospheric humidity that is based on a selected surface resistivity of the transparent conductor, and causing the solvent to at least partially evaporate such that the plurality of conductive components remains overlying the substrate.