HVAC Acid Neutralizing Composition With Water-Scavenging Drying Agents

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Solution Overview

Problem

Air-conditioning and refrigeration systems face recurring compressor burnout due to acid formation in the compressor fluid, which leads to corrosion and system degradation, with existing acid neutralizers often resulting in incomplete reactions and re-formation of acids.

Innovation Solution

A composition containing an acid neutralizer or scavenger, such as metal alkoxide or inorganic bases, combined with a hydrolytic drying agent like orthoformates, drives reactions to completion, ensuring acid removal and prevention of re-formation, thereby addressing the incomplete reactions and corrosion issues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing acid neutralizers are used in HVAC systems, then acid neutralization is achieved, but reactions are incomplete and acids re-form

Engineering Contradiction:
Improveacid neutralization effectivenessVSAvoidduration of acid-free state
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces a drying agent as an intermediary substance that works in conjunction with the acid neutralizer. The drying agent absorbs water produced during neutralization, preventing it from participating in reverse reactions that would regenerate acids. This intermediary component ensures the neutralization reaction proceeds to completion and remains stable over time.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the system by adding a drying agent that alters the equilibrium conditions of the neutralization reaction. By removing water (changing the concentration parameter), the reaction is driven toward complete neutralization according to Le Chatelier's principle, preventing acid re-formation.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If acid neutralizers are added to lubricating oil, then acid attack is reduced, but corrosion and system degradation continue

Engineering Contradiction:
Improveacid attack on system partsVSAvoidsystem component integrity
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The drying agent acts as an intermediary that removes the byproduct (water) of the neutralization reaction. By eliminating water, the system prevents the formation of new acids and ensures that the neutralized state is maintained, thereby protecting system components from ongoing corrosion and degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the harmful byproduct of neutralization (water, which can promote further acid formation) into a beneficial outcome by using the drying agent to absorb it. This transforms what would be a harmful element into an opportunity to drive the neutralization reaction to completion and maintain system integrity.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Quantity of substance

If neutralization reactions occur in HVAC systems, then acids are neutralized, but reactions are equilibrium-controlled and do not proceed to completion

Engineering Contradiction:
Improveamount of acid neutralizedVSAvoidcompletion of neutralization reaction
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The drying agent serves as an intermediary that continuously removes water from the reaction environment. This removal of a reaction byproduct shifts the equilibrium position toward complete neutralization, ensuring that the maximum quantity of acid is converted to salt and water, with the water immediately absorbed by the drying agent.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the reaction parameters by introducing a drying agent that alters the water activity in the system. This parameter change drives the equilibrium-controlled reaction toward completion by continuously removing water, thereby achieving precise and complete neutralization of acids.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively neutralizes and removes acids, preventing re-formation and reducing compressor burnout risks, as demonstrated by significant reductions in acid content in test results, with the combination of potassium hydroxide and triethylorthoformate achieving up to 87% acid reduction.

Implementation Method 1

The amount of acid in the lubricating oil is typically denoted by the total acid number (TAN). The total acid number (TAN) is a measurement of acidity that is determined by the amount of potassium hydroxide in milligrams that is needed to neutralize the acids in one gram of oil.

Methodology Applied
Scientific EffectNeutralization reaction: Chemical Bonding

Implementation Method 2

A composition containing an acid neutralizer or scavenger, such as metal alkoxide or inorganic bases, combined with a hydrolytic drying agent like orthoformates, drives reactions to completion, ensuring acid removal and prevention of re-formation

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS10203138B2Neutralization and removal of acids in HVAC systems through the use of drying agents
Publication Date: 2019.02.12 ALLTEMP PROD CO LTD
  • US10203138B2 patent drawing
  • US10203138B2 patent drawing

AI summary

A composition for neutralizing or removing an acid in a refrigeration or air-conditioning system, the composition comprising a) an acid neutralizer or scavenger such as a metal alkoxide, carbodiimide, glycidyl ether, epoxide, alkanolamine, arylamine, overbased metal sulphonates, or an inorganic base (e.g. KOH); and b) a hydrolytic drying agent such as an orthoester (e.g. triethylorthoformate), acetal, epoxide, or a carbodiimide, whereby the water formed by neutralization is removed from the system. Also disclosed is the use of the composition for neutralizing or removing an acid from a refrigeration or air-conditioning system; and a method for neutralizing or removing an acid from the refrigeration or air-conditioning system.