Hybrid Bonding Plasma Clean With RPS-RF Residue Removal

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Solution Overview

Problem

Copper-dielectric hybrid bonding in semiconductor manufacturing faces challenges such as particle and organic residue removal, void formation due to gaseous outgassing, and physical particulates, which affect bonding quality and reliability.

Innovation Solution

A substrate processing system utilizing a remote plasma source and RF plasma chamber for cleaning and activation, enabling improved hybrid bonding by forming and controlling plasmas to remove residues and particles, and ensuring stable bonding surfaces through tunable and flexible processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If plasma cleaning is performed to remove particles and organic residues, then bonding quality is improved, but processing time and system complexity increase

Engineering Contradiction:
Improvebonding qualityVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The plasma cleaning process is divided into two distinct stages: a first plasma cleaning step using a hydrocarbon-based gas to remove organic residues and form a carbonaceous layer, followed by a second plasma cleaning step using an oxygen-based gas to remove the carbonaceous layer and particles. This segmentation allows each step to be optimized for its specific function, improving overall bonding quality while managing processing time through targeted cleaning actions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first plasma cleaning step performs a preliminary cleaning action by forming a carbonaceous layer on the surface that traps organic residues and particles. This preliminary action prepares the surface for the second cleaning step, ensuring that the final cleaning is more effective and requires less time to achieve the desired bonding quality.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If plasma cleaning is performed to remove particles and organic residues, then bonding quality is improved, but device complexity increases

Engineering Contradiction:
Improvebonding qualityVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The plasma processing system is designed to perform multiple functions using a single apparatus: it can execute the first plasma cleaning step with hydrocarbon-based gas, the second plasma cleaning step with oxygen-based gas, and potentially other semiconductor processing operations. This multi-functionality reduces the need for separate dedicated equipment for each cleaning step, thereby managing device complexity while achieving improved bonding quality.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system manages complexity by changing plasma parameters (gas composition, power levels, pressure, treatment duration) rather than requiring fundamentally different equipment for each cleaning step. The first plasma step uses hydrocarbon-based gas at specific power and pressure conditions, while the second step uses oxygen-based gas with different parameters, allowing one system to handle multiple cleaning requirements through parameter adjustment.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If copper expansion is utilized to eliminate radial-shaped hollows, then bonding reliability is improved, but control over topography and defectivity becomes more difficult

Engineering Contradiction:
Improvebonding reliabilityVSAvoidtopography control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The dual plasma cleaning process is performed as a preliminary action before hybrid bonding to remove particles and organic residues from the copper surface. This preliminary cleaning ensures that copper expansion during bonding occurs on a clean surface, eliminating radial-shaped hollows and improving bonding reliability while maintaining control over topography and defectivity through proper surface preparation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The plasma cleaning parameters (gas composition, power, pressure, duration) are optimized to clean the copper surface without altering its topography or causing defects. By carefully controlling these parameters, the process removes contaminants while preserving the surface characteristics needed for reliable copper expansion during hybrid bonding.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system enhances bonding yields, reduces defectivity, and extends hardware lifetime, achieving high-throughput integration with reduced costs and improved mean time between failures in advanced semiconductor packaging.

Implementation Method 1

dissociate a gas in the at least one radical generator to form a plasma, flow the plasma into the processing volume

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

dissociate a gas in the at least one radical generator to form a plasma

Methodology Applied
Scientific EffectGas dissociation: Photodissociation

Implementation Method 3

bias the substrate support using the radio frequency generator to create a second plasma

Methodology Applied
Scientific EffectRadio frequency plasma generation: Electromagnetic Induction

Data Source

PatentUS20240412948A1Methods and apparatus for RPS-RF plasma clean and activation for advanced semiconductor packaging
Publication Date: 2024.12.12 APPLIED MATERIALS INC
  • US20240412948A1 patent drawing
  • US20240412948A1 patent drawing
  • US20240412948A1 patent drawing

AI summary

Embodiments of the disclosure provided herein include a system and method for plasma cleaning and activation using hybrid bonding. The system includes a processing chamber, a substrate support configured to support a substrate during hybrid bonding substrate processing, a gas delivery system coupled to the processing chamber having at least one radical generator, and a controller configured to cause the substrate processing system to form a first layer on a first substrate, dissociate a gas in the at least one radical generator to form a plasma, flow the plasma into the processing volume of the processing chamber for a period of time, exhaust the plasma, by products, and effluent gas from the processing volume after the period of time, and adhere a second layer disposed on a second substrate onto the first layer using a hybrid bonding technique.