Hybrid Chemical Sensor Stability in Polymeric Matrices

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Solution Overview

Problem

Existing chemical sensors lack thermal and mechanical stability, making them incompatible with polymeric matrices during processing and limiting their effectiveness in industrial applications, particularly at high temperatures and shear forces.

Innovation Solution

Development of organic-inorganic hybrid chemical sensors with thermal and mechanical stability, achieved through sol-gel reaction techniques using alkoxides, which are incorporated into polymeric matrices via conventional extrusion processes, allowing them to maintain functionality and respond to environmental changes by color change.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional chemical sensors are used, then they can detect chemical compounds, but they lack thermal and mechanical stability during polymer processing

Engineering Contradiction:
Improvethermal and mechanical stabilityVSAvoidcompatibility with polymeric matrices
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies composite materials by combining organic sensor compounds with inorganic sol-gel matrices to create hybrid sensors. This composite structure provides both the chemical sensing functionality of organic compounds and the thermal/mechanical stability of inorganic materials, enabling the sensors to withstand polymer processing conditions while maintaining compatibility with polymeric matrices.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by modifying the chemical composition and structure of sensor materials through sol-gel processing. By controlling parameters such as pH, temperature, and precursor ratios during sol-gel synthesis, the patent creates sensors with optimized thermal stability, mechanical strength, and compatibility characteristics suitable for incorporation into polymeric matrices.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If sensors are incorporated into polymeric matrices via conventional extrusion, then processing becomes feasible, but sensor functionality must be maintained at high temperatures

Engineering Contradiction:
Improveprocessability via extrusionVSAvoidfunctional stability at high temperature
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The sol-gel derived hybrid composite structure provides high-temperature stability while maintaining sensor functionality. The inorganic matrix framework protects the organic sensing compounds from thermal degradation during extrusion processing, enabling the sensors to be incorporated into polymeric matrices via conventional extrusion without losing their detection capabilities.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The sol-gel matrix acts as a protective cushioning structure that shields the sensor compounds from the harsh thermal and mechanical conditions of extrusion processing. This pre-formed robust matrix structure prevents sensor degradation before the sensors are even incorporated into the polymeric matrix, ensuring functionality is maintained throughout the manufacturing process.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Measurement precision

If sol-gel technology is used to prepare sensors, then surface area and purity are improved, but thermal and mechanical stability must be enhanced

Engineering Contradiction:
Improvedetection sensitivityVSAvoidthermo-mechanical stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent creates organic-inorganic hybrid composite sensors that combine the high surface area and purity advantages of sol-gel materials with the thermal and mechanical stability of cross-linked inorganic networks. This composite approach allows the sensors to maintain high detection sensitivity while achieving the thermo-mechanical stability required for industrial applications.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the sol-gel process parameters to achieve both high surface area and improved thermal/mechanical stability. By adjusting cross-linking density, drying conditions, and heat treatment parameters, the patent optimizes the pore structure and mechanical strength simultaneously, resulting in sensors that are both sensitive and stable.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensors demonstrate enhanced compatibility and stability within polymeric matrices, enabling their use in industries like food, pharmaceutical, and petrochemical, with effective detection of amine, amide, and oxide-reducing compounds through color changes, even at high temperatures and shear forces.

Implementation Method 1

achieved through sol-gel reaction techniques using alkoxides

Methodology Applied
Scientific EffectSol-gel reaction: Gel

Implementation Method 2

respond to changes in the environment, particularly in the presence of amine and/or amide and/or oxide-reducing compounds, and/or vapor thereof by color change

Methodology Applied
Scientific EffectColor change detection: Thermochromism

Implementation Method 3

incorporated into polymeric matrices via conventional extrusion processes

Methodology Applied
Scientific EffectExtrusion: Extrusion

Data Source

PatentUS9063111B2Hybrid chemical sensor, and, sensitive polymeric composition
Publication Date: 2015.06.23 BRASKEM SA
  • US9063111B2 patent drawing
  • US9063111B2 patent drawing
  • US9063111B2 patent drawing

AI summary

The present invention relates to chemical sensors with hybrid characteristics, which are thermo-mechanically stable and able to respond to changes in the environment, particularly in the presence of amine and/or amide and/or oxide-reducing compounds, and/or vapor thereof by color change, as well as its incorporation into sensitive polymeric composition.