Device for separating and sequestering carbon dioxide in gas mixtures by hydrate method with coupled cold storage

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Solution Overview

Problem

Current carbon capture and sequestration technologies lack integrated systems for mixed gas applications, leading to inefficiencies and high energy consumption, and there is a need for effective methods to minimize energy loss and enhance carbon dioxide sequestration, particularly in ocean environments.

Innovation Solution

A device for separating and storing carbon dioxide using the hydrate method coupled with cold storage, featuring a primary separation trunk circuit and two parallel branches for methane and carbon dioxide recovery, along with a gas hydrate sequestration apparatus and a cold storage system, utilizing a refrigeration cycle and sensing/monitoring equipment to optimize the process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If hydrate method is used for carbon dioxide capture from mixed gases, then separation efficiency is improved, but device complexity increases due to lack of mature integrated systems

Engineering Contradiction:
Improveseparation efficiencyVSAvoiddevice complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The device is divided into multiple independent functional modules including compression modules, heat exchange modules, hydrate formation modules, and decomposition modules. Each module performs a specific function in the carbon dioxide separation process, allowing for modular assembly and operation while achieving high separation efficiency from mixed gases.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The integrated system combines multiple functions into a unified device that can compress, cool, form hydrates, and decompose hydrates all in one system. The device handles mixed gas separation while simultaneously managing temperature and pressure control, making it a multi-functional solution for carbon dioxide capture from various gas sources.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Device complexity

If conventional carbon capture methods are used, then device complexity is reduced, but energy consumption increases

Engineering Contradiction:
Improvedevice complexityVSAvoidenergy consumption
Core Design Contradiction:
Device complexityVSUse of energy by moving object

Solution Approach 1:

The device utilizes the phase transition of carbon dioxide into hydrate form under specific temperature and pressure conditions. By controlling the phase change from gas to hydrate and back to gas during decomposition, the system achieves energy-efficient separation without requiring complex high-energy processes, leveraging natural thermodynamic properties of hydrate formation.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The system optimizes energy consumption by dynamically adjusting temperature and pressure parameters throughout the process. Compression increases pressure while heat exchange modules control temperature to facilitate hydrate formation, and decomposition reverses these parameters to release pure carbon dioxide, creating an energy-efficient cyclic process.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If multi-stage separation is implemented, then carbon dioxide purity is improved, but process time increases

Engineering Contradiction:
Improvecarbon dioxide purityVSAvoidprocess time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The device operates in continuous multi-stage cycles where compression, cooling, hydrate formation, and decomposition occur sequentially without interruption. While one stage is forming hydrates, another stage is decomposing them, maintaining continuous production flow and achieving high purity carbon dioxide output without significant time delays between stages.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The compression and cooling stages prepare the mixed gas in advance before hydrate formation occurs. By pre-compressing and pre-cooling the gas to optimal conditions, the hydrate formation process proceeds rapidly and efficiently, reducing the overall time required for high-purity carbon dioxide separation while ensuring the necessary purity is achieved.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device achieves multi-stage separation of methane and carbon dioxide, reduces refrigeration energy consumption, and enables efficient sequestration of carbon dioxide as a hydrate, with no added chemicals or secondary pollution, offering environmental and economic benefits.

Implementation Method 1

A device utilizing the hydrate method for separating and sequestrating carbon dioxide from mixed gases

Methodology Applied
Scientific EffectHydrate formation: Hydrates

Implementation Method 2

a carbon dioxide hydrate formation reactor and a carbon dioxide hydrate decomposition reactor

Methodology Applied
Scientific EffectHydrate decomposition: Decomposition (biological)

Implementation Method 3

a primary biogas refrigeration cycle heat exchanger... connected to a primary biogas cooling tower for circulating heat exchange

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 4

primary biogas cooling tower for circulating heat exchange... secondary biogas cooling tower for circulating heat exchange

Methodology Applied
Scientific EffectEvaporative cooling: Evaporative Cooler

Data Source

PatentUS12589348B2Device for separating and sequestering carbon dioxide in gas mixtures by hydrate method with coupled cold storage
Publication Date: 2026.03.31 DALIAN UNIV OF TECH
  • US12589348B2 patent drawing

AI summary

A device for separating and sequestrating carbon dioxide coupled with cold storage in mixed gas via hydrate method, which belongs to the technical field of application of natural gas hydrates includes a gas compression device, a refrigeration cycle device, a hydrate formation/decomposition device, a hydrate cold storage device, a water circulation device and a sensing and monitoring device; taking the separation and sequestration of biogas as an example, the refrigeration cycle device enables the cooling of biogas, decomposition of gas at all levels, hydrate, and circulating water to provide the low-temperature conditions required for hydrate formation; the hydrate cold energy storage device can fully use the latent heat of hydrate phase change to provide the required cooling capacity on the user side; the water circulation device can realize the recycling of decomposition water to ensure the continuous formation of hydrate.