Hydrate Gas Separation Mixing Structure for Continuous Gas Capture

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Solution Overview

Problem

Existing hydrate-based gas separation methods face challenges in achieving continuous, large-scale industrial application due to batch operations, incomplete gas capture, and inefficient gas-liquid mixing, leading to rigorous separation conditions and residual target gas in the gas phase.

Innovation Solution

A continuous gas separation system combining hydrate-based and reverse osmosis processes, utilizing a disturbance device with jet mixers, helical pipes, and choking assemblies to enhance gas-liquid mixing, coupled with a hydrate formation loop and membrane separation, enabling efficient and continuous gas separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If batch or semi-batch separation methods are used in laboratory-scale equipment, then hydrate formation can be achieved, but continuous production of purified gas cannot be realized and water solution cannot be recycled

Engineering Contradiction:
Improvecontinuous production of purified gasVSAvoidrequirement for two or more sets of reactors
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent implements continuous operation by designing a single reactor system where gas-liquid slurry flows continuously through the reaction vessel. The system maintains continuous hydrate formation and separation without requiring multiple batch reactors, achieving uninterrupted production of purified gas while enabling water solution recycling through the continuous flow configuration.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The reactor is divided into multiple functional zones including a gas-liquid mixing section, a hydrate formation section, and a separation section. This segmentation allows different processes to occur simultaneously in different parts of the same continuous system, enabling continuous production without requiring multiple separate reactors.

Inventive Principle:
Principle #1Segmentation

2Quantity of substance

If conventional gas-liquid mixing is used, then hydrate formation occurs, but gas-liquid mass transfer efficiency is insufficient leading to residual target gas in the gas phase

Engineering Contradiction:
Improvecomplete gas captureVSAvoidhydrate formation efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent introduces a vibration device that generates radial vibrations in the reaction vessel, creating strong turbulence and enhancing gas-liquid mass transfer. This mechanical vibration increases the contact between gas and liquid phases, improving hydrate formation efficiency and ensuring complete capture of target gas without residual gas remaining in the gas phase.

Inventive Principle:
Principle #18Mechanical vibration

Solution Approach 2:

The system uses a gas-liquid jet mixer that utilizes high-velocity gas and liquid jets to create intense mixing and mass transfer. The pneumatic-hydraulic interaction generates turbulence and enhances the formation of gas hydrates, significantly improving the quantity of target gas captured and the efficiency of hydrate formation.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Manufacturing precision

If separation conditions are made more rigorous to capture more target gas, then gas separation efficiency improves, but the process becomes more complex and less suitable for industrial application

Engineering Contradiction:
Improvegas separation efficiencyVSAvoidseparation conditions complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex separation conditions with a mechanical vibration-based approach. Instead of requiring rigorous control of temperature, pressure, and composition parameters, the system uses radial vibrations to enhance mass transfer and hydrate formation. This substitution maintains high gas separation efficiency while significantly simplifying the operational conditions and making the process more suitable for industrial application.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves improved hydrate formation efficiency, complete gas capture, and suitable large-scale industrial application by enhancing gas-liquid mass transfer and turbulence, overcoming inefficiencies of pure hydrate processes.

Implementation Method 1

The system achieves improved hydrate formation efficiency, complete gas capture, and suitable large-scale industrial application by enhancing gas-liquid mass transfer and turbulence

Methodology Applied
Scientific EffectTurbulence: Turbulence

Implementation Method 2

Natural gas hydrates are an ice-like crystalline compounds formed by water and natural gas at high pressures and low temperatures

Methodology Applied
Scientific EffectHydrate formation: Hydrates

Implementation Method 3

the gas hydrate formation process is a gas-liquid-solid equilibration process

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 4

A continuous gas separation system combining hydrate-based and reverse osmosis processes

Methodology Applied
Scientific EffectReverse osmosis: Reverse Osmosis

Data Source

PatentUS12508559B2Continuous gas separation system combining hydrate-based process and reverse osmosis process and disturbance device
Publication Date: 2025.12.30 CHINA PETROLEUM & CHEMICAL CORP
  • US12508559B2 patent drawing
  • US12508559B2 patent drawing
  • US12508559B2 patent drawing

AI summary

A disturbance device has two jet mixers, which are oppositely disposed in the horizontal direction; a mixing chamber, which is connected between the two jet mixers; and mixing pipes, which are connected below the mixing chamber. The mixing pipes comprise: a central pipe, which is a vertical straight pipe; multiple helical pipes, which are wound in multiple layers and provided outside the central pipe, the diameters of the multiple helical pipes gradually increasing from the inner to outer layers, and multiple flow deflector assemblies being provided at intervals in each helical pipe; and an outer sleeve, which is a straight pipe, the outer sleeve being sleeved outside the outermost helical pipe. A continuous gas separation system combines a hydrate-based process and a reverse osmosis process, using the disturbance device, enables continuous gas separation.