Hydrocarbon Decomposition Catalyst Purity and Regeneration

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Solution Overview

Problem

Existing methods for direct decomposition of hydrocarbons into carbon and hydrogen, such as those using supported catalysts with iron, experience a sudden drop in activity due to catalyst degradation as produced carbon covers the active sites, leading to short reaction maintenance times.

Innovation Solution

A direct decomposition device and method utilizing a catalyst composed of iron particles with a purity of 86% or more, which maintains reaction activity by developing new active sites even when carbon adheres to the catalyst, and includes a reactor configuration with a fluidized bed to physically remove carbon and a catalyst regeneration system to extend operating time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a supported catalyst with iron on a support is used for direct decomposition of hydrocarbons, then the reaction can be initiated, but the activity drops suddenly within 1 hour due to carbon covering the active sites

Engineering Contradiction:
Improvereaction activityVSAvoidreaction maintenance time
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

The invention extracts the iron catalyst from the supported catalyst structure and uses pure iron particles instead. This removes the support material that would be covered by carbon deposits, allowing the iron particles to maintain activity longer as carbon can be removed from their surfaces more effectively.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the physical and chemical parameters of the catalyst by using pure iron particles with specific purity (86% or more) and specific particle size ranges (0.003-0.03 mm). These parameter changes optimize the catalyst's resistance to deactivation by carbon deposits.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of moving object

If pure iron particles with high purity are used as catalyst, then reaction activity is maintained for long time, but catalyst manufacturing precision requirements increase

Engineering Contradiction:
Improvereaction maintenance timeVSAvoidcatalyst purity control
Core Design Contradiction:
Duration of action of moving objectVSManufacturing precision

Solution Approach 1:

The invention specifies precise parameter ranges for the iron particles including purity (86% or more), particle size (0.003-0.03 mm), and other physical properties. These controlled parameters ensure both long reaction maintenance time and manufacturability within industrial precision capabilities.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of high-purity iron particles as catalysts in a fluidized bed reactor configuration significantly extends the maintenance of reaction activity, allowing for sustained hydrogen production and carbon recovery, with the catalyst regeneration system ensuring prolonged device operation.

Implementation Method 1

a catalyst including a plurality of metal particles with an iron purity of 86% or more

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

The reactor is configured to be supplied with a raw material gas containing hydrocarbons

Methodology Applied
Scientific EffectFluidisation: Fluidisation

Data Source

PatentUS20230406701A1Direct decomposition device and direct decomposition method for hydrocarbon
Publication Date: 2023.12.21 MITSUBISHI HEAVY IND LTD
  • US20230406701A1 patent drawing
  • US20230406701A1 patent drawing
  • US20230406701A1 patent drawing

AI summary

A direct decomposition device for hydrocarbons for directly decomposing hydrocarbons into carbon and hydrogen includes a rector containing a catalyst including a plurality of metal particles with an iron purity of 86% or more. The reactor is configured to be supplied with a raw material gas containing hydrocarbons.