Hydrocarbon Addition for Hydrogen Control in Continuous Casting

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Solution Overview

Problem

In continuous steel casting, achieving uniform and consistent heat transfer is challenging due to fluctuations in hydrogen levels in molten steel, which can lead to defects and increased maintenance costs, as hydrogen levels are affected by atmospheric conditions and require complex inventory management of mold powders or refining processes.

Innovation Solution

Adding a hydrocarbon, such as methane, to the molten steel in a ladle metallurgy furnace to increase hydrogen levels between 5 and 9 ppm, ensuring consistent heat transfer during continuous casting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If mold powder composition is varied to control hydrogen levels, then heat transfer rate consistency is improved, but device complexity and operational complexity increase

Engineering Contradiction:
Improveheat transfer rate consistencyVSAvoidmold powder inventory complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent changes the chemical composition parameters of mold powder (specifically carbon content at 5-15% and hydrogen content at 0.5-5%) to optimize heat transfer rate consistency. By adjusting these compositional parameters, the mold powder interacts with hydrogen in the molten steel to maintain stable heat transfer conditions without requiring complex inventory management.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a standardized mold powder composition that can be used consistently across different casting conditions, replacing the need for extensive inventory of specially formulated powders for different hydrogen levels. This single optimized composition serves as a universal solution, reducing both inventory complexity and operational complexity.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Stability of the object's composition

If extensive inventory of mold powders is maintained to control hydrogen levels, then heat transfer rate consistency is improved, but loss of substance and operational complexity increase

Engineering Contradiction:
Improveheat transfer rate consistencyVSAvoidmold powder inventory management
Core Design Contradiction:
Stability of the object's compositionVSLoss of substance

Solution Approach 1:

The patent develops a universal mold powder composition with specific carbon (5-15%) and hydrogen (0.5-5%) content ranges that functions effectively across varying steel compositions and casting conditions. This multi-functional powder replaces the need for multiple specialized powders, reducing inventory requirements and associated losses from storage and handling.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Stability of the object's composition

If trained operator supervision is required to select correct mold powder, then heat transfer rate consistency is improved, but ease of operation decreases

Engineering Contradiction:
Improveheat transfer rate consistencyVSAvoidmold powder selection process
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent creates a self-regulating mold powder system where the optimized composition (carbon: 5-15%, hydrogen: 0.5-5%) automatically interacts with hydrogen in the molten steel to maintain consistent heat transfer rates. This eliminates the need for operator intervention in powder selection, as the powder composition itself provides the necessary control function.

Inventive Principle:
Principle #25Self-service

4Reliability

If hydrogen levels fluctuate in molten metal, then productivity decreases due to defects and breakouts, but heat transfer rate consistency improves with controlled hydrogen

Engineering Contradiction:
Improvecasting defect reductionVSAvoidmaintenance cost and operational efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent implements a feedback mechanism where the mold powder composition (with specific carbon and hydrogen content) interacts with the hydrogen level in molten steel during casting. This interaction creates a self-regulating system that maintains optimal heat transfer rates and prevents hydrogen-related defects, thereby improving both reliability and productivity without requiring external intervention.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method stabilizes heat transfer rates by maintaining optimal hydrogen levels, reducing defects and maintenance costs, while simplifying operational procedures by controlling hydrogen levels directly in the steel composition.

Implementation Method 1

Due to its high mobility, hydrogen can easily diffuse through the lattice of the steel microstructure

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

As the molten metal enters the mold, the steel solidifies at the water cooled mold walls to form a shell

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 3

As the molten metal enters the mold, the steel solidifies at the water cooled mold walls to form a shell

Methodology Applied
Scientific EffectSolidification: Freezing

Implementation Method 4

adding a hydrocarbon to the molten metal in a ladle metallurgy furnace in an amount sufficient to increase hydrogen levels in the molten steel

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS10022785B2Method of continuous casting
Publication Date: 2018.07.17 NUCOR CORP
  • US10022785B2 patent drawing
  • US10022785B2 patent drawing
  • US10022785B2 patent drawing

AI summary

A method of controlling the amount of hydrogen in steel for consistent heat transfer in continuous casting by adding a hydrocarbon to the molten metal. A heat of molten steel is formed in a ladle metallurgy furnace adapted for use in continuous casting. Then, a hydrocarbon is added to the molten metal in the ladle metallurgy furnace in an amount sufficient to increase hydrogen levels in the molten steel for casting. And finally, the molten steel with a desired level of hydrogen is delivered to a caster to continuously cast a steel product.