Hydrocracker Severity Control via Alpha Value

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Solution Overview

Problem

Current hydrocracking operations lack effective methods for optimizing cracking severity and product composition, particularly when dealing with feeds of varying molecular weights, leading to inefficiencies and loss of valuable products.

Innovation Solution

A method is introduced to optimize hydrocracker operation by determining the alpha value of the feed and adjusting conversion promoting conditions to achieve a target molar ratio of hydrocarbon molecules, allowing for precise control of diesel-to-naphtha ratios and overall production adjustments in response to market conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional hydrocracking operations use fixed conversion monitoring methods, then operational simplicity is maintained, but manufacturing precision of product composition deteriorates

Engineering Contradiction:
Improveproduct composition controlVSAvoidcontrol method complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by introducing the alpha value (α) as a new control parameter that characterizes feed composition. By monitoring and adjusting operating conditions based on alpha value, the system achieves precise control of product composition (diesel-to-naphtha ratios) while adapting to varying feedstocks. This transforms the fixed conversion monitoring into a dynamic parameter-based control system.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements feedback control by continuously monitoring hydrocracker conversion and comparing it against target values derived from alpha value and desired product specifications. The system adjusts operating conditions (temperature, pressure, space velocity) based on this feedback loop, enabling precise manufacturing of product composition while maintaining operational simplicity through automated control.

Inventive Principle:
Principle #23Feedback

2Adaptability or versatility

If hydrocracker operates with fixed severity conditions, then operational simplicity is maintained, but adaptability to varying feed composition deteriorates

Engineering Contradiction:
Improvefeed composition adaptabilityVSAvoidoperational complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The system uses alpha value as a dynamic parameter that automatically adjusts to varying feed compositions. By establishing relationships between alpha value, feed characteristics, and optimal operating conditions, the system adapts to different feeds (Fischer-Tropsch products, heavy oils, residues) without requiring manual recalibration, thus improving adaptability while maintaining ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by pre-establishing the relationship between alpha value and optimal hydrocracking conditions. Before actual hydrocracking operations, the system determines the alpha value of the feed and calculates the corresponding target conversion and operating parameters, allowing the hydrocracker to be pre-configured for the specific feed composition, thereby simplifying subsequent operations.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If conventional conversion monitoring is used, then measurement simplicity is maintained, but manufacturing precision of conversion control deteriorates

Engineering Contradiction:
Improveconversion control precisionVSAvoidconversion measurement complexity
Core Design Contradiction:
Manufacturing precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent introduces alpha value as an intermediary parameter that bridges feed composition characteristics and hydrocracking conversion control. Instead of directly measuring complex product distribution to determine conversion, the system uses alpha value (derived from feed analysis) as an intermediary to calculate target conversion, simplifying measurement while improving precision of conversion control.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system transitions from monitoring absolute conversion values to monitoring conversion relative to alpha value-based targets. By expressing conversion as a function of alpha value and desired product composition, the system achieves more precise conversion control that accounts for feed variations, while maintaining measurement simplicity through standardized analytical methods.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the production of desired hydrocarbon products by optimizing hydrocracker severity and product composition, improving efficiency and profitability by adjusting hydrocracker and Fischer-Tropsch reactor conditions to match market demands.

Implementation Method 1

reacting the synthetic heavy hydrocarbon feed with hydrogen in a hydrocracker under conversion promoting conditions so as to form a hydrocracked effluent comprising a diesel and a naphtha

Methodology Applied
Scientific EffectHydrocracking: Catalysis

Implementation Method 2

the syngas is converted into hydrocarbons. More specifically, the Fischer-Tropsch reaction is the catalytic hydrogenation of carbon monoxide to produce any of a variety of products ranging from methane to higher alkanes and aliphatic alcohols

Methodology Applied
Scientific EffectFischer-Tropsch synthesis: Catalysis

Data Source

PatentUS7282139B2Optimization of gas-to-liquids hydrocracker
Publication Date: 2007.10.16 PHILLIPS 66 CO
  • US7282139B2 patent drawing
  • US7282139B2 patent drawing
  • US7282139B2 patent drawing

AI summary

A method for optimal production of synthetic diesel and naphtha from a hydrocracker includes hydrocracking a synthetic heavy hydrocarbon feed comprising an α value so as to form a diesel and a naphtha; selecting a desired diesel-to-naphtha ratio; calculating, based on the feed α and the desired diesel-to-naphtha ratio, a target molar ratio of hydrocarbons exiting to hydrocarbons entering the hydrocracker; and adjusting at least one hydrocracking conversion promoting condition so as to achieve said target molar ratio. The present invention further relates to a method for adjusting the overall production of a syngas-to-synthetic hydrocarbons plant in response to market conditions, comprising adjusting at least one hydrocracking conversion promoting condition and/or at least one conversion promoting condition within a Fischer-Tropsch reactor so as to maintain the overall diesel-to-naphtha ratio or to maintain a diesel production rate within a predetermined range of a desired value.