Hydrocracking Catalyst Pore Volume via Composite Support

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current hydrocracking catalysts face challenges in effectively processing high-boiling hydrocarbon feeds due to limited pore volume and accessibility of reactant molecules, particularly with molecular sieves and metal sulfides, which require enhancement of the catalyst's porous structure to improve conversion efficiency.

Innovation Solution

A hydrocracking catalyst is developed using a support comprising an acidic silica-alumina component and alumina derived from a pseudo-boehmite component, with specific X-ray diffraction and infrared spectrogram characteristics, along with zeolite molecular sieves and metal components like nickel and molybdenum, to enhance pore volume and surface area, improving the catalyst's performance in converting aromatic hydrocarbons.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of stationary object

If molecular sieve and metal sulfides are used as catalyst support, then the catalyst structure is stable, but the pore volume is small and accessibility of reactant molecules is limited

Engineering Contradiction:
Improvepore volumeVSAvoidaccessibility of reactant molecules
Core Design Contradiction:
Volume of stationary objectVSEase of operation

Solution Approach 1:

The patent uses a composite support structure combining molecular sieve (zeolite) with metal sulfides and alumina. This composite material integrates the stability of molecular sieve with the porous structure of alumina, creating a support that provides both structural stability and adequate pore volume for reactant accessibility. The composite nature allows synergistic effects where each component contributes its advantageous properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs porous alumina as a key component of the support structure. The alumina provides a porous matrix with controlled pore size distribution that enhances the accessibility of reactant molecules to active sites. The porous structure of alumina complements the molecular sieve structure, creating a hierarchical pore system that facilitates mass transport while maintaining catalytic activity.

Inventive Principle:
Principle #31Porous materials

2Ease of operation

If pore diameter of support is increased to improve accessibility, then reactant accessibility improves, but catalyst strength and stability may be compromised

Engineering Contradiction:
Improveaccessibility of reactant moleculesVSAvoidcatalyst strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent creates different pore size regions within the catalyst structure. The alumina component provides larger pores for bulk mass transport and accessibility, while the molecular sieve provides smaller, uniform pores for selective catalysis. This local differentiation of pore sizes allows the catalyst to simultaneously achieve good accessibility and maintain structural integrity through the hierarchical pore architecture.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The catalyst structure implements a nested pore system where the molecular sieve units are embedded within the alumina matrix. This nested arrangement creates a hierarchical pore structure where larger alumina pores provide access to smaller molecular sieve pores, enabling reactants to reach active sites while the outer structure maintains mechanical strength and stability.

Inventive Principle:
Principle #7Nested doll (Nesting)

3Volume of stationary object

If heat-resistant inorganic oxide matrix with large pore volume is introduced, then pore volume increases, but device complexity increases

Engineering Contradiction:
Improvepore volumeVSAvoidcatalyst structure complexity
Core Design Contradiction:
Volume of stationary objectVSDevice complexity

Solution Approach 1:

The patent merges the molecular sieve component with the alumina support in a integrated composite structure. Rather than treating them as separate components requiring complex assembly, the molecular sieve is incorporated into the alumina matrix during catalyst preparation, creating a unified structure where both components work synergistically. This merging approach increases pore volume while avoiding the complexity of multi-component assembly.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst demonstrates improved performance in hydrodearomatization, reducing aromatic hydrocarbons in hydrocarbon oils by up to 30% compared to prior art catalysts, with enhanced pore structure and metal distribution optimizing reactant accessibility.

Implementation Method 1

said support is obtained by mixing, moulding, drying and calcining the acidic silica-alumina component with the pseudo-boehmite component

Methodology Applied
Scientific EffectPhase transformation: Crystallisation

Implementation Method 2

at least one element of the VIB group and at least one element of the VIII group as hydrogenation metals

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9469817B2Hydrocracking catalyst and use of the same
Publication Date: 2016.10.18 CHINA PETROLEUM & CHEMICAL CORP
  • US9469817B2 patent drawing
  • US9469817B2 patent drawing
  • US9469817B2 patent drawing

AI summary

A hydrocracking catalyst comprises a support, at least one of VIII Group metal components, and at least one of VIB Group metal components. The support comprises an acidic silica-alumina component and alumina derived from a pseudo-boehmite component, wherein the content of the acidic silica-alumina component is 3-80 wt %, the content of alumina derived from the pseudo-boehmite component is 20-95 wt %, based on the support. The support is obtained by mixing, molding, drying and calcining the acidic silica-alumina component with the pseudo-boehmite component, wherein said pseudo-boehmite component comprises pseudo-boehmite PB1 and pseudo-boehmite PB2, wherein the content of PB1 is 10-90 wt % and the content of PB2 is 0-60 wt % on a dry basis and based on the support.