Hydrodepolymerization Catalyst for Plastic Waste Recycling

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Solution Overview

Problem

Current methods for recycling polymeric waste materials, such as pyrolysis, face challenges in achieving high yield and energy efficiency, particularly in reducing aromatic and olefinic content, which limits the direct use of hydrodepolymerization products as feedstock for further processing without additional purification.

Innovation Solution

A process involving the hydrodepolymerization of polymeric waste using a hydrocracking catalyst composed of a hydrogenating component with metals like Fe, Mo, W, Ti, Ni, Cr, V, Co, Zr, supported on an inorganic carrier, combined with an acidic depolymerizing component, under controlled hydrogen pressure and temperature, to produce a hydrodepolymerization product with reduced aromatic and olefinic content, suitable for steam cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If pyrolysis is used to convert plastic waste into chemical intermediates, then waste plastics materials can be recycled, but the aromatic and olefinic content in the products is high requiring additional purification

Engineering Contradiction:
Improverecycling capabilityVSAvoidproduct purity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent combines depolymerization and hydrogenation functions into a single catalyst system containing both acidic components (for depolymerization) and metal components (for hydrogenation). This merged approach allows simultaneous breakdown of polymer chains and reduction of aromatic/olefinic content in one reactor, eliminating the need for separate purification steps while achieving both recycling capability and product purity

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The catalyst system uses composite material structure combining acidic components (such as zeolites or alumina) with metal components (such as nickel, palladium, or platinum) supported on inorganic carriers. This composite catalyst enables dual functionality - depolymerization of plastic waste and hydrogenation to reduce aromatic and olefinic content - thereby resolving the contradiction between ease of manufacture and manufacturing precision

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional recycling methods are used, then polymeric waste can be processed, but energy efficiency and yield are limited

Engineering Contradiction:
Improverecycling yieldVSAvoidenergy efficiency
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent employs parameter changes by conducting hydrodepolymerization under controlled hydrogen pressure (1-100 bar) and temperature (200-500°C) conditions, which optimize both reaction efficiency and energy utilization. The metal catalyst components facilitate hydrogenation reactions that proceed more efficiently under these controlled parameters, improving both productivity and energy efficiency compared to conventional thermal pyrolysis

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces purely thermal mechanical energy input (conventional pyrolysis) with a catalytic chemical system that uses hydrogen and metal catalysts to drive depolymerization and hydrogenation. This substitution of mechanical/thermal processing with catalytic chemical processing improves energy efficiency and yields by lowering activation energy requirements and enabling more complete conversion of plastic waste to useful products

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enhances the yield and energy efficiency of recycling polymeric waste, producing a hydrodepolymerization product with low aromatic and olefinic content, enabling direct use as feedstock for steam cracking without further purification, thereby improving the recycling efficiency and product quality.

Implementation Method 1

a hydrogenating component made from or containing a metal selected from the group consisting of Fe, Mo, W, Ti, Ni, Cr, V, Co, Zr, and mixtures thereof

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Implementation Method 2

mixing the feedstock of polymeric waste material with a hydrocracking catalyst made from or containing a hydrogenating component... and a depolymerizing component being an acidic compound

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

a depolymerizing component being an acidic compound... depolymerizing the mixture in the presence of hydrogen in a reactor

Methodology Applied
Scientific EffectDepolymerization: Decomposition (biological)

Implementation Method 4

mixing the feedstock of polymeric waste material with a hydrocracking catalyst made from or containing... a depolymerizing component being an acidic compound

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 5

depolymerizing the mixture in the presence of hydrogen in a reactor at a hydrogen pressure from 20 to 500 bar

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS20240117141A1Process for hydrodepolymerization of polymeric waste material
Publication Date: 2024.04.11 BASELL POLIOLEFINE ITALIA SRL
  • US20240117141A1 patent drawing

AI summary

A process for the hydrodepolymerization of polymeric waste material at a hydrogen pressure from 20 to 500 bar, with a hydrocracking catalyst made from or containing (a) a hydrogenating component made from or containing a metal selected from the group consisting of Fe, Mo, W, Ti, Ni, Cr, V, Co, Zr, and mixtures thereof, supported on an inorganic carrier, and (b) a depolymerizing component being an acidic compound.