Hydrogel Bead for Hydrofluoric Acid Detection

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Solution Overview

Problem

Existing methods for detecting hydrofluoric acid are expensive, inconvenient to store and transport due to their liquid form, and lack a clear visual indication of concentration, posing safety challenges in industrial applications.

Innovation Solution

A hydrogel bead impregnated with an organometallic ligand compound that changes color reversibly with hydrofluoric acid concentration, comprising a mixture of an aromatic organic compound with a metal-ligand compound, which is easy to prepare and use, forming a porous bead that can be stored and transported conveniently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If liquid detection methods are used, then detection capability is achieved, but storage and transport convenience deteriorates

Engineering Contradiction:
Improvedetection capabilityVSAvoidstorage and transport convenience
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The patent encapsulates the liquid detection reagents within a hydrogel bead matrix, transforming the liquid state into a semi-solid gel state that maintains reagent functionality while enabling easy handling, storage, and transport without spillage or contamination risks

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The invention creates a composite hydrogel bead system combining multiple functional components (detection reagents, hydrogel matrix, porous structure) into a single integrated unit that provides both detection capability and operational convenience

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If conventional detection reagents are used, then detection function is provided, but cost increases

Engineering Contradiction:
Improvedetection functionVSAvoidcost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent modifies the physical state parameter of the detection reagents from liquid to gel form, which enables the use of simpler, more cost-effective packaging and delivery systems while maintaining the chemical detection functionality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The hydrogel beads are designed as disposable single-use detection units that eliminate the need for expensive storage infrastructure, complex handling equipment, and repeated calibration, thereby reducing overall system cost

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Measurement precision

If detection method provides concentration information, then measurement accuracy improves, but visual clarity deteriorates

Engineering Contradiction:
Improveconcentration informationVSAvoidvisual indication clarity
Core Design Contradiction:
Measurement precisionVSIllumination intensity

Solution Approach 1:

The patent employs colorimetric detection where the hydrogel bead changes color in response to hydrofluoric acid concentration, providing both quantitative concentration information and clear visual indication simultaneously through distinct color transitions at different concentration levels

Inventive Principle:
Principle #32Color changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hydrogel bead provides a clear visual indication of hydrofluoric acid concentration, is cost-effective, and easy to carry, enabling safe and efficient detection of hydrofluoric acid in industrial settings.

Implementation Method 1

an organometallic ligand compound that reversibly changes color depending on the concentration of hydrofluoric acid when coming into contact with hydrofluoric acid

Methodology Applied
Scientific EffectColor change: Thermochromism

Implementation Method 2

a porous bead impregnated with an organometallic ligand compound

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS10067104B2Method for preparing hydrogel bead for detection of hydrofluoric acid and kit comprising the same
Publication Date: 2018.09.04 IND ACADEMIC COOP FOUND YONSEI UNIV
  • US10067104B2 patent drawing
  • US10067104B2 patent drawing
  • US10067104B2 patent drawing

AI summary

The present invention relates to a hydrogel bead for detecting hydrofluoric acid and a kit comprising the same, and more particularly, to a hydrogel bead capable of detecting hydrofluoric acid using an organometallic ligand compound that reversibly changes color depending on the concentration of hydrofluoric acid when coming into contact with hydrofluoric acid, and to a kit for detecting hydrofluoric acid comprising the same. In an embodiment, a method for preparing a hydrogel bead for detecting hydrofluoric acid comprises the steps of: mixing an organic compound, which contains an aromatic functional group having at least one hydroxyl group bonded thereto, with a solution of a metal-ligand compound that bonds with the organic compound, thereby preparing a mixed solution; dropping the mixed solution onto a gelling agent; and adding coagulating agent to the mixture resulting from the dropping step to form a porous bead.