Hydrogel Buoy for Long-Term Algaecide Release in Water

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Solution Overview

Problem

Existing algaecide treatments for cyanobacterial harmful algal blooms (CHABs) suffer from rapid concentration decay, necessitating frequent reapplication, which is costly and poses risks to operators and the environment, while current sustained release technologies are expensive, limited in duration, and can displace from application sites.

Innovation Solution

A buoyant device with a hydrogel-based payload reservoir that allows controlled release of algaecides through a hydrogel diffusion barrier, enabling sustained release over months and allowing for reuse, localization, and easy removal from water bodies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If algaecide is applied all at once, then immediate algicidal effect is achieved, but concentration decays rapidly requiring frequent reapplication

Engineering Contradiction:
Improvealgicidal effect durationVSAvoidtime between reapplications
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent changes the physical state and release parameters of the algaecide by incorporating it into a buoyant device with controlled release mechanisms. The algaecide is released gradually over time through diffusion and degradation of the device matrix, transforming from immediate high-concentration release to sustained low-concentration release, thereby extending the algicidal effect duration without requiring frequent reapplication

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The buoyant device provides continuous release of algaecide over extended periods (weeks to months) through controlled degradation and diffusion processes. The device maintains effective algicidal concentrations in the water column continuously, eliminating the gaps between applications that occur with traditional batch applications, thus achieving uninterrupted useful action

Inventive Principle:
Principle #20Continuity of useful action

2Reliability

If frequent reapplication of algaecide is performed, then sustained algicidal effect is maintained, but operational costs and chemical exposure risks increase

Engineering Contradiction:
Improvesustained algicidal effectVSAvoidoperator exposure risk
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The buoyant device is designed to be self-contained and autonomously releases algaecide over extended periods without requiring operator intervention. The device floats independently, maintains its position in the water column, and provides continuous release through its degradation and diffusion mechanisms, thereby eliminating repeated manual applications and reducing operator exposure risks while maintaining reliable algicidal effect

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The algaecide is pre-loaded into the buoyant device during manufacturing, and the device is deployed in advance to provide sustained release. This preliminary preparation eliminates the need for frequent subsequent applications by operators, reducing their exposure risk while maintaining the reliability of the algicidal effect through the device's time-controlled release mechanism

Inventive Principle:
Principle #10Preliminary action

3Duration of action of moving object

If coated copper sulfate granules are used for sustained release, then release duration is extended, but manufacturing cost increases significantly

Engineering Contradiction:
Improvealgaecide release durationVSAvoidmanufacturing cost
Core Design Contradiction:
Duration of action of moving objectVSEase of manufacture

Solution Approach 1:

The patent changes the release mechanism from coated granules to a buoyant device with controlled degradation and diffusion. The device uses readily available materials and simple construction methods (inflation of containers, attachment of components) to achieve extended release, avoiding the expensive coating processes required for copper sulfate granules while maintaining comparable or superior release duration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The buoyant device is designed as a disposable unit that is inexpensive to manufacture and deploy. The device undergoes controlled degradation over its service life, becoming less functional over time, which is acceptable for a single-use disposable system. This approach avoids the high manufacturing costs of coated granules while providing adequate release duration for the application period

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Adaptability or versatility

If specialized synthetic polymer gels are used for stimulus-responsive release, then targeted release is achieved, but device complexity and material cost increase

Engineering Contradiction:
Improvestimulus-responsive releaseVSAvoidpolymer specialization requirement
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent achieves stimulus-responsive release through simple physical parameter changes in the buoyant device design rather than complex specialized polymers. The device responds to environmental conditions (light, temperature, water flow) through basic material properties and geometric design, providing targeted release without requiring expensive or complex specialized polymer chemistry

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The buoyant device uses simple, readily available materials that do not require specialized polymer synthesis. The device is designed to be inexpensive and disposable, avoiding the high costs and complexity of specialized polymer gels while still achieving adequate stimulus-responsive behavior through basic physical principles and geometric design

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

5Duration of action of moving object

If gel beads or micro-particles are used for algaecide encapsulation, then controlled release is achieved, but displacement by water currents and sedimentation occurs

Engineering Contradiction:
Improvecontrolled release timeVSAvoidposition stability
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The buoyant device incorporates buoyant materials and design features that counteract the downward forces of water currents and gravity-induced sedimentation. The device is designed to float and maintain its position in the water column, using buoyancy forces to oppose the displacement effects that would otherwise cause gel beads and micro-particles to sink or be carried away by currents

Inventive Principle:
Principle #8Anti-weight (Counterweight)

Solution Approach 2:

The buoyant device uses flexible yet durable container structures that protect the algaecide payload while allowing controlled release. The flexible shell design provides structural integrity to resist displacement by water currents while maintaining the controlled release function, preventing the premature sinking or displacement that occurs with rigid gel beads and micro-particles

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The buoy provides long-term, targeted algaecide release, reducing the need for frequent applications, minimizing environmental impact, and lowering costs by being reusable and removable, while maintaining effective algacidal effects.

Implementation Method 1

a gel disk assembly disposed within the first arm, wherein the gel disk assembly comprises a hydrogel; wherein a payload within the reservoir is capable of exiting the buoy upon diffusion of the payload through the hydrogel

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20250376392A1Devices for Long-Term Controlled Release of Payloads in Aqueous Environments
Publication Date: 2025.12.11 UNIVERSITY OF TOLEDO
  • US20250376392A1 patent drawing
  • US20250376392A1 patent drawing
  • US20250376392A1 patent drawing

AI summary

A buoy for the sustained release of a payload, such as an algaecide, into an aqueous environment is described. For the buoy to release the payload into the aqueous environment, the payload diffuses through a hydrogel fixedly housed within the buoy.