Hydrogel-Coated Proppants for Self-Suspension in Hydraulic Fracturing

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Solution Overview

Problem

Current proppant systems in hydraulic fracturing face challenges such as settling issues, high viscosity requirements, cost, health and safety concerns, and reduced fracture conductivity due to the use of resin-coated proppants and additives, which affect the efficiency and safety of oil and gas production.

Innovation Solution

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles, providing self-suspension properties, reduced friction, and improved adhesion, while maintaining conductivity and resisting closure stresses, are used in conjunction with oxidative or enzymatic breakers to enhance their performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If high viscosity fluid is used to suspend proppants, then proppant suspension stability is improved, but pumping energy requirements increase

Engineering Contradiction:
Improveproppant suspension stabilityVSAvoidpumping energy requirements
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The invention changes the physical-chemical parameters of proppant particles by coating them with hydrophilic polymers, transforming them from hydrophobic to hydrophilic. This parameter change allows proppants to remain suspended in low viscosity, water-based fluids without requiring high viscosity carriers, thereby reducing pumping energy while maintaining suspension stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The hydrophilic polymer coating acts as an intermediary between the proppant particles and the aqueous fracturing fluid. This intermediary layer provides steric stabilization and prevents particle aggregation, enabling stable suspension in low viscosity fluids without requiring high viscosity carriers

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If resin-coated proppants are used, then fracture conductivity is improved, but health and safety concerns increase due to fines formation

Engineering Contradiction:
Improvefracture conductivityVSAvoidfines formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention uses composite proppant structures consisting of a proppant core coated with hydrophilic polymer materials. This composite structure provides both the mechanical strength needed for fracture conductivity and the surface properties that prevent fines generation, replacing the traditional resin coating approach

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention employs oxidative breakers to accelerate the degradation of hydrocarbon contaminants and organic materials in the fracturing fluid and formation. This oxidation process eliminates harmful substances without requiring resin-coated proppants, thereby maintaining fracture conductivity while reducing fines formation and health safety concerns

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

3Strength

If high proppant loading levels are used, then fracture support is improved, but suspension stability deteriorates

Engineering Contradiction:
Improvefracture supportVSAvoidsuspension stability
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

By changing the surface properties of proppant particles through hydrophilic coating, the invention enables stable suspension at high proppant loading levels. The modified surface parameters prevent particle aggregation and settling, allowing high concentrations of proppant to remain suspended without requiring increased viscosity

Inventive Principle:
Principle #35Parameter changes

4Use of energy by moving object

If slickwater fluid is used, then pumping energy is reduced, but proppant suspending capability deteriorates

Engineering Contradiction:
Improvepumping energyVSAvoidproppant suspending capability
Core Design Contradiction:
Use of energy by moving objectVSStability of the object's composition

Solution Approach 1:

The invention changes the surface parameters of proppant particles by applying hydrophilic polymer coatings, transforming them from hydrophobic sand grains to hydrophilic suspended particles. This parameter change enables effective suspension in low viscosity slickwater fluids, combining the energy efficiency of slickwater with the suspending capability of high viscosity fluids

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hydrogel-coated proppants remain suspended in less viscous fluids, reduce equipment erosion, and improve well production efficiency, safety, and environmental impact by maintaining fracture conductivity and reducing fines formation, thus simplifying hydraulic fracturing operations.

Implementation Method 1

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles

Methodology Applied
Scientific EffectHydrogel swelling: Hydrogel

Implementation Method 2

The viscosity of the fluid is typically managed by addition of synthetic or naturally-based polymers

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles, providing self-suspension properties, reduced friction

Methodology Applied
Scientific EffectFriction reduction: Friction

Implementation Method 4

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles, providing self-suspension properties, reduced friction, and improved adhesion

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 5

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles, providing self-suspension properties, reduced friction, and improved adhesion, while maintaining conductivity and resisting closure stresses, are used in conjunction with oxidative or enzymatic breakers

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 6

Modified proppants with a hydrogel coating that localizes on the surface of proppant particles, providing self-suspension properties, reduced friction, and improved adhesion, while maintaining conductivity and resisting closure stresses, are used in conjunction with oxidative or enzymatic breakers

Methodology Applied
Scientific EffectEnzymatic hydrolysis: Enzyme

Data Source

PatentUS10472943B2Self-suspending proppants for hydraulic fracturing
Publication Date: 2019.11.12 COVIA SOLUTIONS LLC
  • US10472943B2 patent drawing
  • US10472943B2 patent drawing
  • US10472943B2 patent drawing

AI summary

The invention provides for modified proppants, comprising a proppant particle and a hydrogel coating, wherein the hydrogel coating localizes on the surface of the proppant particle to produce the modified proppant, methods of manufacturing such proppants and methods of use.