Conductive Hydrogel Electrodes for Wearable Health Monitors

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Solution Overview

Problem

Existing skin-based sensing platforms are stiff and rigid, failing to conform to the human body's complex contours and requiring electrolytic gels that can irritate the skin and dry out, leading to poor signal quality and limited long-term monitoring capabilities.

Innovation Solution

A conductive hydrogel electrode composed of a polyvinyl alcohol-based hydrogel with dynamic covalent boronic ester bonds and biocompatible polymers, incorporating conductive fillers like MXene, CNTs, and PEDOT:PSS, which is flexible, adhesive, and has low impedance, allowing for improved compatibility and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metallic or silicon electrodes are used, then conductivity is achieved, but the material becomes stiff and rigid, failing to conform to complex body contours

Engineering Contradiction:
ImproveconductivityVSAvoidconformability to body contours
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent employs a hydrogel matrix that forms a flexible, conformable layer capable of adapting to complex body contours. This hydrogel shell encapsulates the conductive elements, providing both flexibility and electrical functionality, thereby resolving the contradiction between maintaining conductivity and achieving conformability.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The invention uses composite materials combining hydrogel with conductive fillers (such as carbon nanotubes, graphene, or metallic particles). This composite structure integrates the flexibility and conformability of hydrogel with the electrical conductivity of the embedded conductive materials, simultaneously achieving both desired properties.

Inventive Principle:
Principle #40Composite materials

2Reliability

If electrolytic gels are applied to reduce impedance, then skin contact impedance decreases, but skin irritation occurs and the gel dries out over time

Engineering Contradiction:
ImproveimpedanceVSAvoidskin irritation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs a disposable electrode design where the entire electrode including the conductive interface is replaced after a single use. This eliminates the problem of gel drying out and skin irritation from prolonged exposure, as the electrode is discarded after one application, ensuring consistent performance without long-term harmful effects.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention changes the physical and chemical parameters of the conductive interface by using a hydrogel-based composite material with embedded conductive fillers. This alternative formulation achieves low impedance without relying on traditional electrolytic gels that cause skin irritation and drying, thereby resolving the contradiction between impedance reduction and skin safety.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If traditional electrodes are used, then initial signal quality is acceptable, but signal quality deteriorates over time due to gel drying

Engineering Contradiction:
Improvesignal qualityVSAvoidmonitoring duration
Core Design Contradiction:
Measurement precisionVSDuration of action of stationary object

Solution Approach 1:

The patent implements a disposable electrode designed for single-use application. While the individual electrode has a limited operational lifespan, the system maintains consistent signal quality across multiple patients by replacing the electrode each time, eliminating cumulative degradation issues and ensuring reliable measurements for each monitoring session.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The electrode is pre-configured with optimized conductive materials and hydrogel composition during manufacturing, ensuring that signal quality is maintained at optimal levels throughout its intended usage period. This preliminary optimization of material properties and structure ensures consistent performance without degradation during the monitoring session.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The conductive hydrogel electrodes provide low skin impedance, flexibility, and stability for long-term health monitoring, potentially outperforming current technologies and reducing manufacturing costs, with the ability to record various biopotentials without additional skin treatments.

Implementation Method 1

a first network that comprises at least two hydroxyl-bearing chains of a first polymer, the at least two hydroxyl-bearing polymer chains being crosslinked by crosslinks that comprise one or more boronic ester bonds

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

at least one conductive additive dispersed within the composition

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS20230397870A1Conductive Hydrogel-Based Wearable Health Monitors
Publication Date: 2023.12.14 THE TRUSTEES OF THE UNIV OF PENNSYLVANIA
  • US20230397870A1 patent drawing
  • US20230397870A1 patent drawing
  • US20230397870A1 patent drawing

AI summary

A health monitor, comprising: an electrode that includes a hydrogel composition comprising a first network that comprises at least two hydroxyl-bearing chains of a first polymer, the at least two hydroxyl-bearing polymer chains being crosslinked by crosslinks that comprise one or more boronic ester bonds; and at least one conductive additive dispersed within the composition, the electrode being configured for patient contact. Also provided are related methods.