Hydrogen Occlusive Alloy Composition for Release

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Solution Overview

Problem

Magnesium-based hydrogen occlusive alloys have a disadvantage in releasing very little hydrogen despite occluding a large amount, making them ineffective as hydrogen storage materials.

Innovation Solution

A hydrogen occlusive alloy with a cubic structure and composition represented by (Mg1-XLX)(Ni1-Y-ZMYLiZ), where L and M are specific elements, and mole ratios X, Y, and Z are within certain ranges, enhancing hydrogen release properties while maintaining occlusion capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If alloying elements are added to improve hydrogen release, then hydrogen release properties are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvehydrogen release amountVSAvoidalloy composition complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent establishes specific concentration ranges for each alloying element (0.1-5.0 wt%) to optimize hydrogen release while maintaining manageable manufacturing complexity through defined compositional parameters

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy achieves a remarkable improvement in hydrogen release properties and cycle efficiency, preventing crystalline structure collapse during occlusion and release, allowing for a large hydrogen release amount.

Implementation Method 1

Hydrogen occlusive alloys are alloys which store hydrogen as an energy source safely and easily

Methodology Applied
Scientific EffectHydrogen occlusion: Absorption (physical)

Implementation Method 2

metal elements which exothermically react with hydrogen, that is, which form a stable compound with hydrogen

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS7758805B2Hydrogen occlusive alloy, hydrogen storage film and hydrogen storage tank
Publication Date: 2010.07.20 KK TOSHIBA
  • US7758805B2 patent drawing
  • US7758805B2 patent drawing
  • US7758805B2 patent drawing

AI summary

A hydrogen occlusive alloy has a cubic structure and a composition represented by the following general formula (1):(Mg1-XLX)(Ni1-Y-ZMYLiZ)m  (1)where the element L is at least one element selected from the group consisting of Na, Cs, Ca, Sr, Ba, Sc, Ti, Zr, Hf, V, Nb, Ta, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, the element M is at least one element selected from the group consisting of Cr, Mo, W, Mn, Fe, Co, Pd, Pt, Cu, Ag, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, Sb and Bi, and mole ratios X, Y, Z and m are 0<X≦0.5, 0<Y≦0.5, 0.1≦Z≦0.9, and 1.8≦m≦2.2, respectively.