Hydrogen Diffusion Barrier in Compound Semiconductor TFTs

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Solution Overview

Problem

Thin film transistors (TFTs) using amorphous silicon have low mobility, while those using polysilicon have non-uniform threshold voltage and require expensive manufacturing processes, and compound semiconductors like zinc oxide exhibit high resistivities and high contact resistance, which complicates their use in high-speed circuits and large-area substrates.

Innovation Solution

A thin film transistor design that includes a hydrogen diffusion barrier layer on the channel region to prevent hydrogen from diffusing into the channel, allowing higher hydrogen concentrations in the source and drain regions, reducing resistivity and contact resistance, while maintaining low resistivity in the channel region, using a semiconductor layer of oxygen-containing compound semiconductors like zinc oxide doped with gallium, indium, or tin, and a hydrogen diffusion barrier layer of nitrides or carbides.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen is implanted into compound semiconductor to reduce resistivity, then contact resistance decreases, but leakage current increases due to hydrogen in channel region

Engineering Contradiction:
Improvecontact resistanceVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent segments the semiconductor layer into distinct functional regions: a channel region and source/drain regions. By implanting hydrogen selectively into the source and drain regions while avoiding the channel region, the patent reduces contact resistance at the electrodes without increasing leakage current in the channel, thus resolving the technical contradiction.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by creating different hydrogen concentration profiles in different regions of the semiconductor layer. The source and drain regions have high hydrogen concentration to reduce contact resistance, while the channel region maintains low hydrogen concentration to prevent leakage current, optimizing both electrical characteristics simultaneously.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If amorphous silicon is used for semiconductor layer, then manufacturing is simpler, but mobility is low making high-speed circuits difficult

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcarrier mobility
Core Design Contradiction:
Ease of manufactureVSSpeed

Solution Approach 1:

The patent changes the material parameter from amorphous silicon to compound semiconductor (such as zinc oxide or tin oxide). This material substitution enables higher carrier mobility suitable for high-speed circuits while maintaining compatibility with low-temperature manufacturing processes, thus resolving the contradiction between manufacturing simplicity and device speed.

Inventive Principle:
Principle #35Parameter changes

3Speed

If polysilicon is used for semiconductor layer, then mobility is high, but threshold voltage is non-uniform requiring additional compensating circuits

Engineering Contradiction:
Improvecarrier mobilityVSAvoidthreshold voltage uniformity
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent changes the semiconductor material from polysilicon to compound semiconductor (zinc oxide, tin oxide, or their alloys). This material substitution provides both high carrier mobility for fast switching and uniform threshold voltage characteristics, eliminating the need for additional compensating circuits while maintaining high-speed performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design improves the electrical characteristics of TFTs by reducing contact resistance and preventing increased leakage current, enabling better performance in high-speed circuits and large-area substrates with reduced manufacturing complexity and cost.

Implementation Method 1

a hydrogen diffusion barrier layer on the semiconductor layer, the hydrogen diffusion barrier layer covering the channel region and exposing the source and drain regions

Methodology Applied
Scientific EffectHydrogen diffusion barrier: Diffusion Barrier

Implementation Method 2

Implanting hydrogen (H) atoms into the compound semiconductor may reduce the resistivity the semiconductor layer

Methodology Applied
Scientific EffectHydrogen diffusion: Diffusion

Data Source

PatentUS8871566B2Method of manufacturing thin film transistor
Publication Date: 2014.10.28 SAMSUNG DISPLAY CO LTD
  • US8871566B2 patent drawing
  • US8871566B2 patent drawing
  • US8871566B2 patent drawing

AI summary

A thin film transistor includes a gate electrode, a first insulating layer on the gate electrode, a semiconductor layer on the gate electrode and separated from the gate electrode by the first insulating layer, the semiconductor layer including a channel region corresponding to the gate electrode, a source region, and a drain region, a hydrogen diffusion barrier layer on the semiconductor layer, the hydrogen diffusion barrier layer covering the channel region and exposing the source and drain regions, and a second insulation layer on the source and drain regions and on the hydrogen diffusion barrier layer, such that the hydrogen diffusion barrier layer is between the second insulation layer and the channel region.