Metastable Hydrogen Carrier Rate Control via Temperature Feedback

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Solution Overview

Problem

Controlling the rate of hydrogen release from metastable hydrogen carriers is challenging due to their temperature and composition dependence, which can lead to unbalanced hydrogen supply for fuel cells, requiring venting or starvation.

Innovation Solution

A method that relates the rate of hydrogen release to the temperature and composition of metastable hydrogen carriers, using equations and look-up tables to adjust the temperature and composition to match the demand, ensuring stable hydrogen supply.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the hydrogen release rate is increased to meet fuel cell demand, then the hydrogen supply improves, but the pressure becomes too high requiring venting to the environment

Engineering Contradiction:
Improvehydrogen release rateVSAvoidexcessive hydrogen pressure
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent implements a feedback control system that continuously monitors the hydrogen release rate and adjusts the temperature of the metastable hydrogen carrier accordingly. The controller receives signals about the actual hydrogen release rate and modifies the heating power to maintain the desired release rate, preventing both excessive pressure buildup and insufficient supply to the fuel cell.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the temperature parameter of the metastable hydrogen carrier to control the hydrogen release rate. By dynamically adjusting the temperature through controlled heating, the system can modulate the decomposition rate of the hydrogen carrier, thereby controlling the hydrogen release rate to match fuel cell demand without causing excessive pressure.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If the hydrogen release rate is decreased to control pressure, then the pressure stability improves, but the fuel cell or energy conversion device becomes starved of hydrogen

Engineering Contradiction:
Improvehydrogen pressure stabilityVSAvoidhydrogen supply to fuel cell
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The feedback control system monitors both the hydrogen release rate and the pressure levels, adjusting the temperature to maintain stable pressure while ensuring sufficient hydrogen supply. When pressure drops or fuel cell demand increases, the controller increases heating power to accelerate hydrogen release, preventing starvation of the fuel cell while maintaining overall pressure stability.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts the temperature and hydrogen release rate based on real-time conditions rather than maintaining a static state. The controller continuously modifies the heating power to balance pressure stability with fuel cell demand, allowing the system to adapt to changing operational requirements and prevent both pressure excursions and hydrogen starvation.

Inventive Principle:
Principle #15Dynamics

3Ease of operation

If temperature control is added to regulate hydrogen release, then the hydrogen supply control improves, but the device complexity increases

Engineering Contradiction:
Improvehydrogen release controlVSAvoidtemperature control system
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The system uses the inherent temperature dependence of the hydrogen release rate from the metastable hydrogen carrier to achieve self-regulation. The metastable hydrogen carrier naturally exhibits increased hydrogen release at higher temperatures, providing an intrinsic control mechanism that reduces the need for complex external control systems. The controller simply needs to modulate heating power, leveraging the material's natural properties for control.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively controls the hydrogen release rate, maintaining optimal pressure and supply for fuel cells, enhancing their performance and efficiency.

Implementation Method 1

a method of controlling a rate of hydrogen release from a decomposition reaction of a metastable hydrogen carrier

Methodology Applied
Scientific EffectDecomposition reaction: Decomposition (biological)

Implementation Method 2

adjusting the temperature according to the relating of the rate and the determining of the composition

Methodology Applied
Scientific EffectThermal control: Heating

Data Source

PatentUS11165083B1Method of controlling rate of hydrogen release from metastable hydrogen carriers
Publication Date: 2021.11.02 HRL LAB
  • US11165083B1 patent drawing
  • US11165083B1 patent drawing
  • US11165083B1 patent drawing

AI summary

According to an embodiment of the present disclosure, a method of controlling a rate of hydrogen release from a decomposition reaction of a hydrogen carrier includes: relating the rate to a temperature and a composition of the metastable hydrogen carrier; determining the composition of the metastable hydrogen carrier; and adjusting the temperature according to the relating of the rate and the determining of the composition.