Hydrogen Production System with CO2 Recycling

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Solution Overview

Problem

Current hydrogen production methods, such as catalytic chemical reactions of methane, result in high carbon dioxide emissions, which contribute to global warming, and are limited by geographical and climatic conditions, making stable hydrogen production challenging.

Innovation Solution

A hydrogen production system utilizing a mixed reforming method that recycles unreacted carbon dioxide as a reactant, incorporating a desulfurization unit, pre-reforming unit, mixed reforming unit, and carbon dioxide capture unit to reduce carbon dioxide discharge and increase overall carbon efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If steam reforming method is used to produce hydrogen, then hydrogen production efficiency is improved, but carbon dioxide emissions increase significantly

Engineering Contradiction:
Improvehydrogen production efficiencyVSAvoidcarbon dioxide emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent captures carbon dioxide that would otherwise be emitted as waste and converts it into a useful reactant for the mixed reforming process. The captured CO2 is fed back into the reforming reactor where it reacts with methane to produce additional hydrogen, thereby transforming a harmful emission into a beneficial resource that enhances both hydrogen production and carbon utilization efficiency.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Instead of discarding carbon dioxide emissions into the atmosphere, the system recovers and recycles the CO2 back into the production process. The carbon dioxide capture unit separates CO2 from the reforming effluent, and this recovered CO2 is then fed back to the mixed reforming reactor, creating a closed-loop system that maximizes carbon utilization and minimizes emissions.

Inventive Principle:
Principle #34Discarding and recovering

2Object-generated harmful factors

If carbon dioxide capture and storage (CCS) is implemented, then carbon dioxide emissions are reduced, but the system requires specific geological structures and locations

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidgeographical adaptability
Core Design Contradiction:
Object-generated harmful factorsVSAdaptability or versatility

Solution Approach 1:

Rather than storing captured CO2 in geological formations, the system converts it into a valuable reactant for hydrogen production. This approach eliminates the need for specific geological structures and makes CO2 reduction technology applicable anywhere hydrogen production occurs, significantly improving geographical adaptability while maintaining effective CO2 emission reduction.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The system uses the captured CO2 to serve the production process itself by feeding it back as a reactant in the mixed reforming reaction. This self-service approach allows the system to reduce its own emissions while enhancing its own productivity, eliminating dependence on external geological storage infrastructure and enabling deployment in diverse locations.

Inventive Principle:
Principle #25Self-service

3Object-generated harmful factors

If renewable energy is used for hydrogen production, then carbon dioxide discharge is minimized, but stable power production becomes difficult due to weather variability

Engineering Contradiction:
Improvecarbon dioxide dischargeVSAvoidpower stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The mixed reforming process with CO2 recycling creates a more stable and continuous hydrogen production system compared to direct renewable electrolysis. By using thermal processes with heat integration and CO2 recirculation, the system can maintain consistent production rates less susceptible to weather fluctuations, while still achieving low CO2 emissions through the carbon recycling mechanism.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The system changes the operational parameters by using thermal energy and chemical reactions rather than direct electrical conversion. The mixed reforming process operates at elevated temperatures with controlled CO2 partial pressures, creating a more stable chemical environment for hydrogen production that is less sensitive to external weather variability while maintaining environmental benefits.

Inventive Principle:
Principle #35Parameter changes

4Object-generated harmful factors

If mixed reforming with CO2 recycling is implemented, then carbon dioxide emissions are reduced and carbon efficiency is improved, but system complexity increases

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidsystem complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges the carbon dioxide capture function with the hydrogen production process by integrating the CO2 capture unit and recycler directly into the reforming system. This combined approach allows CO2 separation and recycling to occur within the same production facility, reducing the need for separate, standalone systems and thereby limiting the increase in overall system complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The mixed reforming reactor serves multiple functions: it produces hydrogen from methane, utilizes captured CO2 as a reactant, and maintains flexible operation with various hydrocarbon feeds. This multi-functionality consolidates what could be separate processes into a single versatile unit, reducing the number of components needed and limiting the increase in system complexity while achieving superior CO2 emission reduction.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively reduces carbon dioxide emissions by 47% or more, enhancing carbon efficiency and stability in hydrogen production, while being adaptable to various environments, making it a more environmentally friendly and economically viable option compared to traditional methods.

Implementation Method 1

a desulfurization unit configured to remove a sulfur component from hydrocarbon gas

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a pre-reforming unit configured to convert hydrocarbons having two or more carbon atoms into methane (CH4) by reacting the hydrocarbon gas with water (H2O) vapor

Methodology Applied
Scientific EffectSteam reforming: Chemical Transport Reactions

Implementation Method 3

a mixed reforming unit configured to produce hydrogen (H2) and carbon monoxide (CO) by performing a mixed reforming reaction between the reaction product of the pre-reforming unit and carbon dioxide (CO2)

Methodology Applied
Scientific EffectMixed reforming reaction: Chemical Transport Reactions

Implementation Method 4

a first heat exchange unit configured to generate water vapor supplied to the pre-reforming unit using the heat of the reaction product of the mixed reforming unit

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 5

a separation unit for separating hydrogen (H2) and carbon monoxide (CO) from the reaction product of the mixed reforming unit

Methodology Applied
Scientific EffectGas separation:

Data Source

PatentUS20240351873A1Hydrogen production system
Publication Date: 2024.10.24 HYUNDAI MOTOR CO LTD
  • US20240351873A1 patent drawing
  • US20240351873A1 patent drawing
  • US20240351873A1 patent drawing

AI summary

A hydrogen production system includes a desulfurization unit configured to remove a sulfur component from hydrocarbon gas. The system has a pre-reforming unit configured to convert hydrocarbons having two or more carbon atoms into methane (CH4) by reacting the hydrocarbon gas with water (H2O) vapor. The system has a mixed reforming unit configured to produce hydrogen (H2) and carbon monoxide (CO) by performing a mixed reforming reaction between the reaction product of the pre-reforming unit and carbon dioxide (CO2). The system has a separation unit for separating hydrogen (H2) and CO from the reaction product of the mixed reforming unit. The system has a first heat exchange unit configured to generate water vapor supplied to the pre-reforming unit using the heat of the reaction product of the mixed reforming unit.