Hydrogen Embrittlement Sensor with Closed Cavity

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Solution Overview

Problem

Current methods for assessing hydrogen embrittlement in industrial equipment are inadequate, as they often rely on hydrogen flow measurements that do not accurately predict the risk of cracking, which can lead to sudden and unpredictable equipment failures due to the localized and rapid nature of crack propagation.

Innovation Solution

A sensor with a closed cavity connected to a pressure measuring device is integrated into the equipment, measuring the equilibrium pressure of hydrogen inside the cavity, which correlates directly with the hydrogen activity in the metal, allowing real-time verification of the hydrogen content against a known threshold to anticipate potential cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If hydrogen flow measurement methods are used to assess hydrogen embrittlement, then the measurement process is simple, but the accuracy of predicting cracking risk is insufficient

Engineering Contradiction:
Improvecracking risk prediction accuracyVSAvoidsensor structure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent introduces a closed cavity as an intermediary structure between the metal component and the pressure measurement device. This cavity accumulates hydrogen gas that diffuses through the metal, converting the difficult-to-measure hydrogen concentration in the metal into an easily measurable pressure in the cavity. The cavity acts as a mediator that translates the hidden hydrogen embrittlement parameter into an observable pressure signal.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces complex electrochemical or spectroscopic measurement systems with a simple pressure measurement system. Instead of using complex devices to directly measure hydrogen concentration in the metal, the invention uses a pressure sensor to measure the pressure of hydrogen gas accumulated in a closed cavity, which is a much simpler and more reliable measurement approach.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If periodic inspection methods are used to detect cracks, then the equipment can be monitored, but the sudden and localized nature of crack propagation makes detection unreliable

Engineering Contradiction:
Improvecrack detection reliabilityVSAvoidtime for crack detection
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent implements preliminary action by continuously monitoring hydrogen pressure in the cavity before cracking occurs. The sensor detects hydrogen accumulation and embrittlement risk in advance, allowing preventive measures to be taken before the sudden crack propagation that characterizes traditional inspection methods. This shifts the detection timing from after crack initiation to before it becomes critical.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent establishes a feedback mechanism where the pressure measurement continuously reflects the current hydrogen embrittlement state of the metal. This real-time feedback allows the system to adapt and alert operators when hydrogen concentration approaches critical levels, enabling dynamic response rather than relying on fixed periodic inspection schedules.

Inventive Principle:
Principle #23Feedback

3Productivity

If hydrogen concentration threshold is used to assess embrittlement risk, then the assessment is straightforward, but it cannot provide real-time verification in service conditions

Engineering Contradiction:
Improvereal-time monitoring capabilityVSAvoidsensor integration complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent makes the sensor system universal by designing it to work with any metal component subjected to hydrogen embrittlement risk. The same basic cavity-and-pressure-sensor structure can be applied to pipes, pressure vessels, and other equipment, making it a multi-functional solution that doesn't require component-specific complex instrumentation.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The sensor system is self-service in that it automatically measures and reports hydrogen embrittlement status without requiring external intervention. The pressure measurement occurs continuously and automatically, and the system self-calibrates against the known threshold, providing autonomous real-time verification during equipment service.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides a direct measurement of the risk of hydrogen embrittlement, enabling early detection of potential cracking and preventing equipment failures by accurately determining the hydrogen activity and pressure thresholds, thus ensuring the safety and reliability of industrial equipment.

Implementation Method 1

Penetration into the metal of hydrogen from the external environment leads to the diffusion of hydrogen into the metal of the sensor, then to its recombination into hydrogen gas inside the closed cavity

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

The stationary pressure measurement reached in this cavity is then indicative of the activity of hydrogen in the steel

Methodology Applied
Scientific EffectPressure measurement:

Data Source

PatentEP3374754B1Sensor for measuring the embrittlement of steels by hydrogen in an aggressive environment, said sensor comprising a metal cavity connected to a pressure-measuring device
Publication Date: 2022.08.31 IFP ENERGIES NOUVELLES
  • EP3374754B1 patent drawingFigure 1~1
  • EP3374754B1 patent drawingFigure 2
  • EP3374754B1 patent drawingFigure 3

AI summary

The invention relates to a sensor device for evaluating the risk of embrittlement by hydrogen for a given metal in an aggressive environment that promotes the penetration of hydrogen into the metal, said sensor consisting of a metal body comprising a closed cavity connected to a pressure-measuring device.