Hydrogen-Gated Resistive Memory for Multi-State Conductivity Control

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Solution Overview

Problem

Current resistive memory devices face limitations in increasing the number of resistance states, magnitude ratio, linearity, symmetry, and driving speed, which hinders their performance.

Innovation Solution

The electronic device incorporates a substrate with operating electrode layers, a channel layer, a proton conductive layer, a hydrogen source layer, and a control electrode layer, where hydrogen is introduced and controlled to alter the work function of the electrode layers, changing the electrical contact characteristics and conductivity, enabling multiple resistance states and efficient signal storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional resistive memory devices are used, then the basic memory function is achieved, but the number of resistance states is limited

Engineering Contradiction:
Improvenumber of resistance statesVSAvoidstorage capacity
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent changes the physical-chemical parameters of the operating electrode layers by controlling hydrogen introduction and release. By adjusting the hydrogen concentration in the operating electrode layers, the work function and electrical contact characteristics are modified, enabling multiple resistance states (at least 3 distinct states) to be achieved in the memory device.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a proton conductive layer as an intermediary component between the hydrogen source layer and the operating electrode layers. This proton conductive layer facilitates controlled hydrogen ion transport, enabling precise modulation of the operating electrode layers' electrical properties and achieving multiple stable resistance states.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If the resistance states are increased, then the storage capacity is improved, but the magnitude ratio between resistance states decreases

Engineering Contradiction:
Improvenumber of resistance statesVSAvoidmagnitude ratio between resistance states
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating different hydrogen concentration profiles in different regions or layers. The hydrogen source layer provides hydrogen locally, and the proton conductive layer enables selective hydrogen transport to specific operating electrode layers, allowing each layer to achieve optimal local electrical contact characteristics for distinct resistance states with sufficient magnitude separation.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If hydrogen is introduced to change work function, then the electrical contact characteristics are altered, but the device structure becomes more complex

Engineering Contradiction:
Improveelectrical contact controlVSAvoidlayer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent implements multi-functionality by designing the proton conductive layer to serve multiple purposes: it acts as a hydrogen transport medium, a barrier to uncontrolled hydrogen diffusion, and a structural element that maintains device integrity. The operating electrode layers also serve dual functions as both electrodes and active elements whose electrical properties are modulated by hydrogen concentration, reducing the need for separate functional components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the resistive memory device's performance by increasing the number of resistance states, improving linearity and symmetry, and accelerating driving speed through controlled hydrogen interaction, effectively addressing existing limitations.

Implementation Method 1

a proton conductive layer disposed over the first and second electrode layers and the channel layer

Methodology Applied
Scientific EffectProton conduction: Conduction (electrical)

Implementation Method 2

hydrogen is introduced and released to change the work function of the operating electrode layers, altering the electrical contact characteristics and conductivity

Methodology Applied
Scientific EffectWork function modulation by hydrogen: Adsorption

Data Source

PatentUS20230309427A1Electronic device having resistance change property
Publication Date: 2023.09.28 SK HYNIX INC
  • US20230309427A1 patent drawing
  • US20230309427A1 patent drawing
  • US20230309427A1 patent drawing

AI summary

An electronic device according to an embodiment of the present disclosure includes a substrate, a base electrode layer disposed over the substrate, first and second operating electrode layers disposed over the base electrode layer to be spaced apart from each other, a channel layer disposed between the first operating electrode layer and the second operating electrode layer over the base electrode layer, a proton conductive layer disposed over the first and second electrode layers and the channel layer, a hydrogen source layer disposed over the proton conductive layer, and a control electrode layer disposed over the hydrogen source layer.