Hydrogen Generation System Using Alkali Metal Reactants

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Solution Overview

Problem

Current hydrogen production methods are inefficient and costly, with high-temperature processes being particularly expensive and lacking in industrial applicability, while existing chemical water splitting processes using alkali and alkaline earth metals have limitations in scalability and efficiency.

Innovation Solution

A system and process utilizing a structural material to support primary and boost reactants, along with a moderator and diffuser material, to facilitate a spontaneous and controlled hydrogen generation from water through a chain reaction, where liquid water reacts with alkali or alkaline earth metals to produce hydroxides, which then react with metal boost reactants at room temperature to generate additional hydrogen, using materials like sodium, silicon, and barium salts to achieve high purity and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If high-temperature processes are used for hydrogen production, then hydrogen generation is achieved, but the process becomes costly and lacks industrial applicability

Engineering Contradiction:
Improvereaction temperatureVSAvoidprocess cost
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The invention changes the temperature parameter from high-temperature processes to room temperature operation. This is achieved by using solid state reactants (alkali metals, alkaline earth metals, or their hydrides) that can react with water at ambient conditions, eliminating the need for expensive high-temperature equipment and energy input while maintaining hydrogen generation capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs disposable solid state reactant cartridges containing alkali metals, alkaline earth metals, or their hydrides. These single-use cartridges eliminate the need for expensive, complex high-temperature system infrastructure, making the process economically viable for industrial applications while maintaining safety and control

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Productivity

If existing chemical water splitting processes using alkali and alkaline earth metals are used, then hydrogen generation is achieved, but scalability and efficiency are limited

Engineering Contradiction:
Improvehydrogen generation efficiencyVSAvoidscalability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The invention segments the hydrogen generation system into modular, self-contained cartridges that can be independently operated and scaled. Each cartridge contains pre-measured amounts of reactants in a controlled geometry, allowing the system to be scaled by simply adding or removing cartridges rather than redesigning the entire system, thus improving both efficiency and scalability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention introduces dynamic control mechanisms including adjustable water flow rates, controllable reactant exposure surfaces, and regulated hydrogen outflow. These dynamic elements allow the system to adapt to different production requirements, improving efficiency through optimized reaction conditions and enabling scalability through flexible operational parameters

Inventive Principle:
Principle #15Dynamics

3Productivity

If reactive metals are used for hydrogen generation, then hydrogen production efficiency increases, but safety concerns arise during transportation and handling

Engineering Contradiction:
Improvehydrogen production efficiencyVSAvoidsafety during transportation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention uses robust, hermetically sealed cartridges with controlled geometry to contain the reactive metals or hydrides. These enclosed structures provide mechanical protection during transportation and handling while preventing accidental contact with moisture, thus maintaining safety without compromising the high reactivity needed for efficient hydrogen production when activated

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The invention performs preliminary preparation by pre-encapsulating the reactive metals or hydrides in controlled geometries with specific surface areas and protective coatings before use. This preliminary action ensures safe transportation and storage while maintaining the ability to rapidly initiate high-efficiency hydrogen production when water is introduced through controlled exposure

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves a high efficiency of at least 90% hydrogen generation with low costs, producing a continuous controlled hydrogen flow suitable for emergency power, propulsion, and portable device charging, with a robust and safe system design.

Implementation Method 1

liquid water reacts with alkali or alkaline earth metals to produce hydroxides

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

hydroxides, which then react with metal boost reactants at room temperature to generate additional hydrogen

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

a diffuser material wherein the water is diffused before reacting with the primary reactant and wherein the hydrogen obtained is permeated

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11383976B2System and process for generating hydrogen
Publication Date: 2022.07.12 DRAGE & MATE INT SL
  • US11383976B2 patent drawing

AI summary

A system is capable to safely generate a continuous controlled hydrogen flow. The passive auto sufficient hydrogen system is very valuable for example for emergency power back up, propulsion application, battery charging or powering portable devices. Also, a chemical process generates hydrogen using alkali metals, alkaline earth metals, hydrides of alkali metals or hydrides of alkaline earth metals to obtain primary by products from water. Then, the primary byproducts react with a metal reactant to obtain additional hydrogen.