Hydrogen Generator Absorbent Exhaust Management

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Solution Overview

Problem

Existing hydrogen generators face challenges in efficiently separating and managing gaseous hydrogen from liquid exhaust products, particularly in orientation-insensitive designs where the liquid exhaust can cause issues.

Innovation Solution

Incorporating an absorbent material that swells upon absorbing the exhaust reaction product, which is capable of immobilizing the liquid and includes a wicking material to distribute it, along with pH-adjusting agents and crystallization promoters to prevent blockages, and a volume exchange mechanism to compensate for volume changes, ensuring the hydrogen generator remains compact and functional.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If an absorbent material is added to immobilize liquid exhaust products, then orientation insensitivity is improved, but device complexity increases

Engineering Contradiction:
Improveorientation insensitivityVSAvoiddevice complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The absorbent material is integrated directly into the existing generator structure, merging the liquid immobilization function with the exhaust product handling system. This eliminates the need for separate orientation control mechanisms and reduces overall device complexity while achieving orientation insensitivity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The absorbent material acts as an intermediary substance that captures and immobilizes liquid exhaust products within the reaction chamber. This mediator enables the generator to function in any orientation by preventing liquid accumulation and maintaining reaction efficiency without requiring complex mechanical orientation control.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If a swelling absorbent material is used to bind liquid exhaust, then liquid immobilization is improved, but volume management becomes challenging

Engineering Contradiction:
Improveliquid binding capacityVSAvoidvolume management
Core Design Contradiction:
Quantity of substanceVSVolume of stationary object

Solution Approach 1:

The absorbent material is designed to dynamically change volume in response to liquid absorption. As the material swells to bind exhaust liquids, its expanded form efficiently occupies and utilizes the available void spaces within the reaction chamber, optimizing both liquid binding capacity and volume utilization without requiring additional space.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The physical parameters of the absorbent material (volume, density, porosity) are allowed to change as it absorbs liquid. This parameter transformation enables the material to adapt its volume to match the available space in the reaction chamber, effectively managing volume constraints while maximizing liquid binding capacity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If pH-adjusting agents and crystallization promoters are added to prevent blockages, then reliability is improved, but device complexity increases

Engineering Contradiction:
Improveblockage preventionVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The absorbent material system incorporates pH-adjusting agents and crystallization promoters that automatically regulate the chemical environment during operation. These components self-regulate to prevent blockages without requiring external control systems, maintaining reliability while avoiding additional complexity through autonomous chemical management.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

Chemical agents serve as intermediaries that mediate between the liquid exhaust products and the absorbent material. These intermediaries adjust pH and promote crystallization to prevent blockages in the exhaust pathways, ensuring reliable operation without requiring mechanical blockage prevention mechanisms.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Volume of stationary object

If volume exchange mechanism is implemented to compensate for swelling, then compact design is achieved, but device complexity increases

Engineering Contradiction:
Improvecompact designVSAvoiddevice complexity
Core Design Contradiction:
Volume of stationary objectVSDevice complexity

Solution Approach 1:

The reaction chamber is segmented into functional zones that accommodate the swelling absorbent material. The volume exchange mechanism divides the chamber space to allow for material expansion in one region while maintaining compact overall dimensions through strategic spatial arrangement and zone optimization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The volume exchange mechanism utilizes dimensional transitions within the reaction chamber to accommodate absorbent material swelling. By allowing the material to expand into available three-dimensional space and utilizing vertical or radial dimensions, the system achieves compact design without requiring proportional increases in all linear dimensions.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively immobilizes liquid exhaust products, maintaining the generator's orientation insensitivity and preventing blockages, allowing for efficient hydrogen production and compact design, with the absorbent material's swelling compensating for volume changes and ensuring continuous operation.

Implementation Method 1

the absorbent material is a material suitable for swelling upon absorbing the exhaust reaction product

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

By swelling, the absorbent material is capable of embedding a high amount of liquid

Methodology Applied
Scientific EffectSwelling: Hydrogel

Implementation Method 3

wicking material such as an absorbing tissue, suitable for distributing the mainly liquid exhaust reaction product in the absorbent material

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 4

agents which promote crystallization of the borates such as probably calcium ions

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS9187322B2Hydrogen generator
Publication Date: 2015.11.17 HORIZON NEW ENERGY TECHNOLOGIES (HONG KONG) LTD
  • US9187322B2 patent drawing
  • US9187322B2 patent drawing
  • US9187322B2 patent drawing

AI summary

A hydrogen generator (1), particularly for supplying a fuel cell, is described comprising a supply (3, 29) of a fuel, i.e. a chemical hydride, which can be hydrolyzed to be reacted in a reaction chamber (14, 33) communicating with the first supply (3, 29) to produce hydrogen gas and an at least partially liquid exhaust reaction product, the reaction chamber communicating with outlet pathways (16, 17) for the hydrogen gas and for the exhaust reaction product, the latter (17) leading to a supply of an absorbent material (21) suitable for immobilizing the exhaust reaction product.