Hydrogen Generator Water Trapping Portion

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Solution Overview

Problem

Conventional hydrogen generators face increased costs and durability issues due to complex steam passage configurations, and the direct supply of liquid water to the reforming catalyst can inhibit reactions and damage the catalyst.

Innovation Solution

A hydrogen generator design featuring an annular preheat evaporator, a water trapping portion, and a reformer with a shift converter, where liquid water is trapped before reaching the reforming catalyst, and heat exchange occurs between the hydrogen-containing gas and liquid water to control temperatures and prevent catalyst cooling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If liquid water is directly supplied to the reforming catalyst, then the steam-reforming reaction can proceed, but the catalyst temperature drops rapidly causing reaction inhibition and catalyst damage

Engineering Contradiction:
Improvesteam-reforming reaction rateVSAvoidcatalyst stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces a water trapping portion that captures liquid water before it reaches the reforming catalyst. This preliminary action prevents the harmful direct contact between liquid water and the catalyst, allowing the steam-reforming reaction to proceed while maintaining catalyst temperature and stability.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If a complex steam passage configuration is used, then steam can be supplied to the reformer, but the system cost increases and durability deteriorates

Engineering Contradiction:
Improvesteam supply capabilityVSAvoidsteam passage structure
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent extracts the water trapping function from the complex steam passage system and implements it as a separate, simple water trapping portion. This simplifies the overall steam passage configuration while maintaining the necessary steam supply capability to the reformer.

Inventive Principle:
Principle #2Taking out (Extraction)

3Use of energy by moving object

If the reformer is positioned directly below the preheat evaporator, then heat exchange efficiency improves, but liquid water from the evaporator directly contacts the reforming catalyst causing damage

Engineering Contradiction:
Improveheat exchange efficiencyVSAvoidcatalyst damage from liquid water
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent introduces the water trapping portion as an intermediary component between the preheat evaporator and the reforming catalyst. This intermediary captures liquid water while allowing heat exchange to continue, thus maintaining thermal efficiency while preventing catalyst damage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration stabilizes hydrogen generation by preventing catalyst inhibition and damage, reducing costs and improving durability, while maintaining optimal reaction temperatures.

Implementation Method 1

an annular preheat evaporator which heats a raw material and water by the combustion gas generated by the heater to generate a mixture gas of the raw material and steam

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

heat exchange occurs between the hydrogen-containing gas and liquid water to control temperatures

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

an annular reformer which is disposed under the preheat evaporator and generates a hydrogen-containing gas by causing the mixture gas generated by the preheat evaporator to pass through a reforming catalyst heated by the combustion gas

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

The reformer uses a material gas, such as city gas or LPG, obtained from, for example, an existing fossil material infrastructure, and steam generated by a water evaporator to progress a steam-reforming reaction at a temperature of 600° C. to 700° C., thereby generating the hydrogen-containing gas

Methodology Applied
Scientific EffectSteam-reforming reaction: Chemical Transport Reactions

Implementation Method 5

The shift converter decreases the temperature of the hydrogen-containing gas and progress a water gas shift reaction at a temperature of 200° C. to 350° C. to reduce the concentration of the carbon monoxide

Methodology Applied
Scientific EffectWater gas shift reaction: Chemical Transport Reactions

Implementation Method 6

the selective oxidizer progresses a selective oxidation reaction at a temperature of 100° C. to 150° C. to further reduce the concentration of the carbon monoxide

Methodology Applied
Scientific EffectSelective oxidation reaction: Oxidation

Implementation Method 7

a heater which combusts a mixture gas of combustion fuel and combustion air to generate a combustion gas

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS8273489B2Hydrogen generator and fuel cell system including the same
Publication Date: 2012.09.25 FUJI ELECTRIC CO LTD
  • US8273489B2 patent drawing
  • US8273489B2 patent drawing
  • US8273489B2 patent drawing

AI summary

A hydrogen generator (100a) includes: a heater (1) which combusts a mixture gas of combustion fuel and combustion air to generate a combustion gas; a preheat evaporator (6) which heats a raw material and water by the combustion gas generated by the heater to generate a mixture gas of the raw material and the water; a reformer (2) which generates a hydrogen-containing gas by causing the mixture gas generated by the preheat evaporator to pass through a reforming catalyst (2a) heated by the combustion gas; and a shift converter (3) which incorporates a shift catalyst (3a) which reduces, by a shift reaction, carbon monoxide contained in the hydrogen-containing gas generated by the reformer, and further includes a water trapping portion (7) which traps liquid water discharged from the preheat evaporator, and the hydrogen generator (100a) is configured to carry out heat exchange between the hydrogen-containing gas supplied from the reformer to the shift converter and the water in the water trapping portion.