Hydrogen Membrane Separation for Pipeline Injection

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Solution Overview

Problem

Current methods for transporting renewable hydrogen from remote locations to end consumers are limited by local regulations and material constraints in natural gas pipelines, which restrict hydrogen content to 5-20 mol %, and existing solutions are energy-intensive or require significant infrastructure investments.

Innovation Solution

A method using membrane separation and Pressure Swing Adsorption (PSA) to adjust hydrogen content from greater than 50 mol % to within the 5-20 mol % range, allowing for high flexibility and efficient transport via existing natural gas pipelines, utilizing commercially available polymeric membranes and PSA units to achieve high hydrogen recovery and purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If hydrogen is injected into existing natural gas pipelines at high concentrations (>50 mol %), then transport capacity and efficiency are improved, but local regulations and material constraints limit the hydrogen content to 5-20 mol %

Engineering Contradiction:
Improvehydrogen transport capacityVSAvoidcompatibility with existing pipeline regulations
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The pipeline system is divided into two segments: a supply pipeline that can accept high hydrogen concentrations (>50 mol %) for efficient transport, and a distribution interface that adjusts hydrogen content to regulatory limits (5-20 mol %) before injection into the existing natural gas grid. This segmentation allows each segment to operate optimally within its own constraints.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

An intermediary adjustment facility is introduced at the interface between the supply pipeline and the existing natural gas grid. This facility uses membrane separation technology to selectively remove hydrogen from the high-concentration stream, producing a regulated stream suitable for grid injection while maintaining the high-capacity transport capability of the supply pipeline.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If hydrogen is transported by dedicated hydrogen pipelines, then transport efficiency and capacity are improved, but huge infrastructure investments are required

Engineering Contradiction:
Improvehydrogen transport efficiencyVSAvoidinfrastructure investment cost
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The existing natural gas pipeline infrastructure is made multi-functional by enabling it to transport both natural gas and hydrogen (or hydrogen-enriched gas) through the use of adjustment facilities. This allows the same physical infrastructure to serve multiple purposes, eliminating the need for separate dedicated hydrogen pipeline construction.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system enables existing natural gas pipelines to serve hydrogen transport needs by providing adjustment capabilities at injection points. The infrastructure adapts to new functions through the addition of relatively simple membrane separation units rather than requiring complete infrastructure replacement.

Inventive Principle:
Principle #25Self-service

3Adaptability or versatility

If hydrogen is liquefied and transported by trailers, then transport flexibility is improved, but energy consumption increases and carbon dioxide emissions occur

Engineering Contradiction:
Improvetransport flexibilityVSAvoidenergy consumption and emissions
Core Design Contradiction:
Adaptability or versatilityVSUse of energy by moving object

Solution Approach 1:

The mechanical transport system (trailers) is replaced with a pipeline-based transport system that uses membrane separation technology for hydrogen management. This substitution eliminates the energy-intensive liquefaction and road transport processes while providing continuous availability and lower carbon emissions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Adaptability or versatility

If membrane separation units are used to adjust hydrogen content, then flexibility in handling fluctuating concentrations is improved, but device complexity increases

Engineering Contradiction:
Improveflexibility with fluctuating hydrogen concentrationsVSAvoidmembrane separation and PSA unit complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The membrane separation units and PSA systems operate by changing physical parameters (pressure, concentration) to achieve hydrogen rejection. By operating within optimized parameter ranges, these systems handle fluctuating feed compositions effectively while maintaining manageable complexity through standardized modular designs.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the long-distance transport of hydrogen via pipelines and direct injection into existing natural gas grids, meeting local regulations while reducing energy consumption and infrastructure costs, with high hydrogen recovery efficiency and flexibility in fluctuating concentrations.

Implementation Method 1

introducing a hydrogen-containing hydrocarbon stream into a membrane separation unit, thereby producing a hydrogen-lean hydrocarbon retentate stream and hydrogen-rich permeate stream

Methodology Applied
Scientific EffectMembrane separation: Semipermeable Membrane

Implementation Method 2

A method using membrane separation and Pressure Swing Adsorption (PSA) to adjust hydrogen content from greater than 50 mol % to within the 5-20 mol % range

Methodology Applied
Scientific EffectPressure Swing Adsorption: Pressure Swing Adsorption

Data Source

PatentUS20240208812A1Method for mixing at least two gases
Publication Date: 2024.06.27 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • US20240208812A1 patent drawing
  • US20240208812A1 patent drawing
  • US20240208812A1 patent drawing

AI summary

A method for separating hydrogen from a hydrogen-containing hydrocarbon stream, including introducing a hydrogen-containing hydrocarbon stream into a membrane separation unit, thereby producing a hydrogen-lean hydrocarbon retentate stream and hydrogen-rich permeate stream. Wherein the hydrogen-containing hydrocarbon stream has greater than 50 mol % hydrogen. And wherein the hydrogen-lean hydrocarbon retentate stream has more than 5 mol % hydrogen and less than 20 mol % hydrogen.