Hydrogen-Olefin Separation with Expansion and Rectification

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Solution Overview

Problem

Existing processes for separating hydrogen from olefin hydrocarbon vapor streams in dehydrogenation units are inefficient and lack comprehensive steps to achieve high purity and recovery rates.

Innovation Solution

A multi-step process involving cooling, separation, isentropic expansion, compression, and rectification to isolate hydrogen from olefin and heavy paraffinic components, utilizing heat exchangers, separators, expanders, and compressors to optimize hydrogen recovery and purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing separation processes are used, then hydrogen separation is achieved, but recovery rate and purity are insufficient

Engineering Contradiction:
Improvehydrogen purityVSAvoidhydrogen recovery rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The separation process is divided into multiple sequential stages: initial cooling and separation, isentropic expansion, compression, and rectification. Each stage targets specific components at different temperature and pressure conditions, enabling progressive purification while maximizing recovery at each step

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process systematically changes temperature and pressure parameters through controlled cooling, isentropic expansion, and compression stages. These parameter variations optimize the physical properties of the vapor stream at each stage, enabling efficient separation of hydrogen from olefin and paraffinic components while maintaining high recovery rates

Inventive Principle:
Principle #35Parameter changes

2Productivity

If simple separation methods are used, then process complexity is low, but separation efficiency is insufficient

Engineering Contradiction:
Improveseparation efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The complex separation task is segmented into distinct operational units (cooling section, separation section, expansion section, compression section, rectification section), each performing a specific function. This modular approach enables high separation efficiency while making the overall complex process manageable and implementable

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Heat exchangers serve as intermediary devices that facilitate heat transfer between different process streams, enabling efficient cooling and temperature control without direct thermal contact. This intermediary approach simplifies the control of complex thermal processes while maintaining high separation efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If comprehensive multi-step process is implemented, then hydrogen purity and recovery are improved, but energy consumption increases

Engineering Contradiction:
Improvehydrogen purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The isentropic expansion stage converts the pressure energy that would otherwise be wasted into useful cooling effect. This naturally cold stream is then used to pre-cool incoming vapor streams in heat exchangers, converting what would be an energy loss into a beneficial cooling source and reducing overall energy consumption

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The process recovers cold energy from expanded streams and uses it to pre-cool incoming feeds through heat exchangers. This recovery of thermal energy from what would otherwise be waste streams significantly reduces the energy input required for the cooling and separation processes

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively separates hydrogen from olefin hydrocarbon vapor streams, achieving high hydrogen recovery and purity, and improving thermodynamic efficiency and stability in dehydrogenation units.

Implementation Method 1

cooling a compressed effluent vapor stream in a heat exchanger

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 2

isentropically expanding, in a high-pressure expander, the second vapor stream, wherein the pressure and temperature of the second vapor stream are lowered

Methodology Applied
Scientific EffectIsentropic expansion: Adiabatic Cooling

Implementation Method 3

compressing, in a high-pressure compressor, the second vapor stream

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 4

isentropically expanding, in a low-pressure expander, the split stream, wherein the pressure and temperature of the split stream are lowered

Methodology Applied
Scientific EffectIsentropic expansion: Adiabatic Cooling

Implementation Method 5

compressing, in a low-pressure compressor, the split stream

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 6

lowering the pressure of the first liquid stream in a control valve

Methodology Applied
Scientific EffectPressure reduction: Pressure Drop

Implementation Method 7

flashing the partially vaporized first liquid stream in a liquid product drum to provide a hydrogen-rich gas

Methodology Applied
Scientific EffectFlashing: Flash Evaporation

Implementation Method 8

combining the hydrogen-rich gas and the second liquid stream in the rectifier, further purifying the hydrogen-rich gas

Methodology Applied
Scientific EffectDistillation: Distillation

Data Source

PatentUS10947171B2Process for separating hydrogen from an olefin hydrocarbon effluent vapor stream
Publication Date: 2021.03.16 ENFLEX INC
  • US10947171B2 patent drawing
  • US10947171B2 patent drawing
  • US10947171B2 patent drawing

AI summary

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a single heat exchanger, multiple gas-liquid separators, multiple expander/compressor sets, and a rectifier attached to a liquid product drum.