Hydrogen-Olefin Separation with Expansion and Rectification
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Solution Overview
Problem
Existing processes for separating hydrogen from olefin hydrocarbon vapor streams in dehydrogenation units are inefficient and lack comprehensive steps to achieve high purity and recovery rates.
Innovation Solution
A multi-step process involving cooling, separation, isentropic expansion, compression, and rectification to isolate hydrogen from olefin and heavy paraffinic components, utilizing heat exchangers, separators, expanders, and compressors to optimize hydrogen recovery and purity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If existing separation processes are used, then hydrogen separation is achieved, but recovery rate and purity are insufficient
Solution Approach 1:
The separation process is divided into multiple sequential stages: initial cooling and separation, isentropic expansion, compression, and rectification. Each stage targets specific components at different temperature and pressure conditions, enabling progressive purification while maximizing recovery at each step
Solution Approach 2:
The process systematically changes temperature and pressure parameters through controlled cooling, isentropic expansion, and compression stages. These parameter variations optimize the physical properties of the vapor stream at each stage, enabling efficient separation of hydrogen from olefin and paraffinic components while maintaining high recovery rates
2Productivity
If simple separation methods are used, then process complexity is low, but separation efficiency is insufficient
Solution Approach 1:
The complex separation task is segmented into distinct operational units (cooling section, separation section, expansion section, compression section, rectification section), each performing a specific function. This modular approach enables high separation efficiency while making the overall complex process manageable and implementable
Solution Approach 2:
Heat exchangers serve as intermediary devices that facilitate heat transfer between different process streams, enabling efficient cooling and temperature control without direct thermal contact. This intermediary approach simplifies the control of complex thermal processes while maintaining high separation efficiency
3Manufacturing precision
If comprehensive multi-step process is implemented, then hydrogen purity and recovery are improved, but energy consumption increases
Solution Approach 1:
The isentropic expansion stage converts the pressure energy that would otherwise be wasted into useful cooling effect. This naturally cold stream is then used to pre-cool incoming vapor streams in heat exchangers, converting what would be an energy loss into a beneficial cooling source and reducing overall energy consumption
Solution Approach 2:
The process recovers cold energy from expanded streams and uses it to pre-cool incoming feeds through heat exchangers. This recovery of thermal energy from what would otherwise be waste streams significantly reduces the energy input required for the cooling and separation processes
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The process effectively separates hydrogen from olefin hydrocarbon vapor streams, achieving high hydrogen recovery and purity, and improving thermodynamic efficiency and stability in dehydrogenation units.
Implementation Method 1
cooling a compressed effluent vapor stream in a heat exchanger
Implementation Method 2
isentropically expanding, in a high-pressure expander, the second vapor stream, wherein the pressure and temperature of the second vapor stream are lowered
Implementation Method 3
compressing, in a high-pressure compressor, the second vapor stream
Implementation Method 4
isentropically expanding, in a low-pressure expander, the split stream, wherein the pressure and temperature of the split stream are lowered
Implementation Method 5
compressing, in a low-pressure compressor, the split stream
Implementation Method 6
lowering the pressure of the first liquid stream in a control valve
Implementation Method 7
flashing the partially vaporized first liquid stream in a liquid product drum to provide a hydrogen-rich gas
Implementation Method 8
combining the hydrogen-rich gas and the second liquid stream in the rectifier, further purifying the hydrogen-rich gas
Data Source
AI summary
One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a single heat exchanger, multiple gas-liquid separators, multiple expander/compressor sets, and a rectifier attached to a liquid product drum.


