Hydrogen Plasma Decapsulation for Silver Wire Integrity

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Solution Overview

Problem

Conventional decapsulation methods, such as acid etching and existing microwave-induced plasma (MIP) etching, cause significant damage to silver and copper bond wires due to the formation of silver oxide and silver fluoride, leading to undesired fracturing and corrosion, especially in electronic devices with silver wire bonding.

Innovation Solution

A hydrogen-containing plasma is used for decapsulation, which is induced by microwaves and directed at the plastic package to etch away the molding compound without damaging the electronic device components, utilizing a gas stream comprising hydrogen as the primary source, often with argon or helium as carrier gases, and optionally including a fluorine source for efficient etching of silica fillers, under atmospheric pressure to prevent ion-induced damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional acid etching or oxygen-based MIP etching is used to remove molding compound, then decapsulation speed is improved, but silver and copper bond wires are damaged due to formation of silver oxide and silver fluoride

Engineering Contradiction:
Improvedecapsulation speedVSAvoidbond wire integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses nitrogen-based plasma instead of oxygen-based plasma to create an inert atmosphere during etching. Nitrogen does not react with silver or copper to form damaging oxides or fluorides, while still enabling effective removal of the molding compound through plasma etching processes.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent changes the chemical composition parameter of the plasma from oxygen-based to nitrogen-based. This fundamental parameter change transforms the chemical reactivity of the plasma, preventing harmful reactions with metal bond wires while maintaining etching capability on the organic molding compound.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If CF4 is used as plasma etchant gas to etch silica fillers, then etching efficiency is improved, but silver fluoride is formed causing wire damage

Engineering Contradiction:
Improveetching efficiencyVSAvoidsilver fluoride formation
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces oxygen-based plasma with nitrogen-based plasma, creating an inert environment that prevents silver fluoride formation. The nitrogen atmosphere does not promote fluoride formation on silver surfaces, eliminating the harmful effect while maintaining etching capability through alternative mechanisms.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent addresses the limitation of nitrogen plasma by combining it with ultrasonic cleaning. The plasma performs the chemical etching of organic material, while ultrasonic cleaning removes the silica fillers that would otherwise remain as residue, converting a potential disadvantage into a beneficial two-step process.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If hydrogen-containing plasma is used for decapsulation, then bond wire damage is reduced, but etching speed decreases compared to oxygen-based MIP

Engineering Contradiction:
Improvebond wire integrityVSAvoidetching speed
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent implements a combined process where nitrogen plasma etching is followed by ultrasonic cleaning in sequence. This continuous action ensures complete removal of both organic molding compound and inorganic silica fillers, compensating for the slower etching speed of nitrogen plasma compared to oxygen plasma.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent introduces ultrasonic cleaning as an intermediary step between plasma treatment and final inspection. This intermediate process removes residual silica particles that the plasma alone cannot efficiently eliminate, achieving complete decapsulation without compromising wire integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hydrogen-containing plasma method effectively decapsulates electronic devices with minimal damage to silver, copper, and other metal bond wires, achieving a smoother and less damaged surface compared to conventional acid decapsulation and oxygen-based MIP etching, while allowing for efficient etching of thicker plastic packages within a reasonable time frame.

Implementation Method 1

microwave-inducing a hydrogen-containing plasma stream from said gas with microwaves

Methodology Applied
Scientific EffectMicrowave induction: Electromagnetic Induction

Implementation Method 2

directing the hydrogen-containing plasma stream to the plastic package to etch the plastic package

Methodology Applied
Scientific EffectPlasma etching: Plasma

Data Source

PatentUS10879079B2Decapsulation of electronic devices
Publication Date: 2020.12.29 JIACO INSTR HLDG BV
  • US10879079B2 patent drawing

AI summary

The invention is directed to a method for treating an electronic device that is encapsulated in a plastic package, said method comprising the steps of providing a gas stream comprising a hydrogen source; inducing a hydrogen-containing plasma stream from said gas; and directing the hydrogen-containing plasma stream to the plastic package to etch the plastic package.